%nprocshared=8
%mem=24000MB
#p wb97xd/genecp opt(ts,calcfc,noeigentest) freq=noraman scrf=(solvent=toluene,smd) nosymm scf(conver=7,xqc,maxcycle=100)

Title Card Required

0 1
 Ru                -0.53757800    0.27602300    0.29529000
 H                 -0.07525100    0.05539200    1.78905700
 P                 -0.42884500    2.61012900    0.71243300
 C                 -1.89968900    3.58578300    0.22223200
 H                 -1.75354700    4.64788800    0.44710100
 H                 -2.06181700    3.44926000   -0.84982300
 H                 -2.77926600    3.22267100    0.76282500
 C                 -0.23290600    3.05013300    2.48132400
 H                  0.68162400    2.60012300    2.87673100
 H                 -0.18908300    4.13666700    2.61357200
 H                 -1.08208500    2.65259900    3.04576000
 C                  0.94619200    3.51329600   -0.09547300
 H                  0.79540500    3.50012300   -1.17811500
 H                  0.97530100    4.55245900    0.24968000
 H                  1.89812400    3.02709300    0.13303900
 C                 -2.13106200    0.18911100    1.08189500
 O                 -3.18942100    0.13512200    1.58156500
 P                 -0.50532100   -2.05616200   -0.06552500
 C                 -1.74442500   -2.64162600   -1.28155600
 H                 -2.75192300   -2.42281500   -0.91539000
 H                 -1.59584100   -2.10872700   -2.22528700
 H                 -1.64929500   -3.71919300   -1.45336900
 C                 -0.80219300   -3.12359600    1.39142300
 H                 -0.77580700   -4.18354200    1.11747200
 H                 -0.03463000   -2.92607700    2.14573500
 H                 -1.77866400   -2.88958700    1.82595200
 C                  1.06637900   -2.70418600   -0.74750300
 H                  1.87985600   -2.52732500   -0.03803900
 H                  0.98521900   -3.77838500   -0.94516300
 H                  1.29164900   -2.17840100   -1.67962200
 C                  2.34883300    0.82595600    4.68752100
 C                  2.34314400    0.32257900    3.39028700
 C                  2.93870800    1.05315200    2.35160500
 C                  3.54849700    2.28487100    2.63242000
 C                  3.54908200    2.78247000    3.93236400
 C                  2.94697400    2.05707200    4.96069400
 H                  1.87911500    0.25973100    5.48624300
 H                  1.86552500   -0.62684300    3.16991600
 H                  4.01143700    2.84901800    1.82824000
 H                  4.01748500    3.73963600    4.14099900
 H                  2.94362000    2.45060500    5.97291500
 C                  2.89034000    0.57130900    1.00161500
 C                  2.83162800    0.20537200   -0.14988400
 H                  2.72796400   -0.09766700   -1.16962400
 O                  0.19544600    0.40525400   -1.73397100
 C                 -0.02626100    1.30737500   -2.62695200
 C                  1.04374200    1.39994500   -3.70389400
 H                  1.24205900    0.41192600   -4.13075300
 H                  0.74768200    2.09125400   -4.49531000
 H                  1.97681900    1.75422600   -3.25000900
 O                 -1.00507600    2.06653100   -2.64166100

Ru
sdd
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-C -H -O -P -Cl
6-31+g*
****

Ru
sdd





