%nprocshared=8
%mem=24000MB
#p wb97xd/genecp opt freq=noraman iop(1/8=5) guess=always scrf=(solvent=toluene,smd) nosymm scf(conver=7,xqc,maxcycle=100)

Title Card Required

0 1
 Ru                -1.32380100    1.01550700   -0.39583700
 P                 -1.68873400    3.35892800   -0.12084600
 C                 -3.36476100    3.91832900   -0.60162600
 H                 -3.43606400    5.00935400   -0.54654200
 H                 -3.56831000    3.58966700   -1.62482000
 H                 -4.11339400    3.48051300    0.06465600
 C                 -1.52219800    4.02523600    1.57724100
 H                 -0.51488900    3.84995100    1.96649700
 H                 -1.72815800    5.10051800    1.59087900
 H                 -2.22571400    3.50755000    2.23522300
 C                 -0.62524900    4.46250500   -1.12582700
 H                 -0.76262400    4.20898600   -2.18053200
 H                 -0.90237600    5.50862100   -0.95892100
 H                  0.42985200    4.32899900   -0.87420200
 C                 -3.12216100    0.78931500   -0.22975500
 O                 -4.26966200    0.65647600   -0.12166500
 P                 -1.10114300   -1.35472800   -0.59482200
 C                 -2.61211600   -2.26136300   -0.08828800
 H                 -2.90807200   -1.94151300    0.91568000
 H                 -3.42980200   -2.04758400   -0.78262800
 H                 -2.42410600   -3.33996100   -0.08208000
 C                  0.14853800   -2.12607800    0.50354900
 H                  0.25238400   -3.19283800    0.27976500
 H                  1.11847200   -1.63909700    0.38780200
 H                 -0.17489500   -2.00565900    1.54157300
 C                 -0.75752200   -2.08669200   -2.23849200
 H                  0.25798600   -1.84761300   -2.56223000
 H                 -0.87403700   -3.17485200   -2.19573500
 H                 -1.45670100   -1.66950300   -2.96840300
 C                 -1.06300900    0.66573500    1.61068700
 C                 -1.95335500    0.55303700    2.61528900
 H                 -0.01469200    0.51772400    1.90145500
 C                 -1.64873900    0.25808100    4.03152000
 H                 -3.01568600    0.71232300    2.41891200
 C                 -2.63391000    0.49014000    5.00558200
 C                 -0.41687400   -0.26171100    4.46638800
 C                 -2.39791000    0.23563700    6.35532200
 H                 -3.60028600    0.88300800    4.69532300
 C                 -0.17715400   -0.51492100    5.81419900
 H                  0.36271600   -0.48311800    3.74212800
 C                 -1.16466200   -0.26660100    6.76978100
 H                 -3.17990700    0.42994400    7.08485100
 H                  0.78425900   -0.91958400    6.12030400
 H                 -0.97690800   -0.46819500    7.82060500
 Cl                -1.63758900    1.45438500   -2.92205200
 C                  0.94109000    1.78214900   -0.07487400
 H                  1.02983900    2.47980600    0.73169900
 C                  1.23348600    1.03713700   -0.99865700
 C                  1.85015200    0.21938800   -2.00941500
 C                  2.77281600   -0.76158600   -1.61322900
 C                  1.59195900    0.42290800   -3.37137900
 C                  3.40226500   -1.55175200   -2.56927500
 H                  2.99940700   -0.89544600   -0.56012900
 C                  2.22886800   -0.37045100   -4.32062400
 H                  0.87245700    1.17663000   -3.66820300
 C                  3.12628900   -1.36211000   -3.92375800
 H                  4.11151000   -2.31176900   -2.25624000
 H                  2.02067600   -0.21470600   -5.37475200
 H                  3.61661000   -1.98159000   -4.66892100

Ru
sdd
****
-C -H -O -P -Cl
6-31+g*
****

Ru
sdd





