%nprocshared=8
%mem=24000MB
#p wb97xd/genecp opt freq=noraman scrf=(solvent=toluene,smd) nosymm scf(conver=7,xqc,maxcycle=100)

Title Card Required

0 1
 Ru                -1.11346000    0.66441400    0.00052300
 P                 -0.76159600    3.00521200    0.23194000
 C                 -2.18345500    3.91252800    0.94686500
 H                 -1.92843900    4.96318800    1.11989500
 H                 -3.03685300    3.86141100    0.26359300
 H                 -2.46780500    3.44828700    1.89573300
 C                  0.60711800    3.44549300    1.36444800
 H                  1.54638600    3.06538100    0.95462600
 H                  0.67645500    4.53225900    1.48070700
 H                  0.43105800    2.98598200    2.34150400
 C                 -0.37953800    3.97437700   -1.27413600
 H                 -1.17559500    3.84300100   -2.01326900
 H                 -0.28017300    5.03832300   -1.03360700
 H                  0.55891100    3.60898400   -1.69998200
 C                 -2.92131000    0.88048700    0.02492300
 O                 -4.07684500    1.00516500    0.09218900
 P                 -1.24009500   -1.70888300   -0.00436100
 C                 -2.89508800   -2.46865300   -0.19535400
 H                 -3.53109500   -2.15879200    0.63988400
 H                 -3.35814200   -2.12340900   -1.12515300
 H                 -2.82901900   -3.56163700   -0.20863500
 C                 -0.58641200   -2.49382100    1.51292100
 H                 -0.57737700   -3.58417500    1.41212200
 H                  0.43159600   -2.13044700    1.68014900
 H                 -1.20160800   -2.20843000    2.37048900
 C                 -0.23282800   -2.50258500   -1.31274900
 H                  0.80810100   -2.19321800   -1.18009900
 H                 -0.30112400   -3.59378100   -1.25027600
 H                 -0.56199300   -2.17289500   -2.30089000
 O                  1.01255100    0.19169200    0.23363700
 O                  2.14681300    1.59354000   -1.10819900
 C                  2.08673700    0.68611100   -0.25208900
 C                  3.37711100    0.11807300    0.31669200
 H                  3.22070100   -0.86913000    0.75765400
 H                  4.14856400    0.07026400   -0.45610500
 H                  3.73427800    0.79314000    1.10377400
 C                 -1.06161300    0.60936800    2.02608400
 C                 -1.99932800    0.77951300    2.97633700
 H                 -0.03984400    0.39270300    2.35752700
 C                 -1.79237100    0.70283200    4.43760400
 H                 -3.03261500    0.98147300    2.68876300
 C                 -2.90748700    0.78640300    5.28797200
 C                 -0.52995800    0.55047700    5.03801900
 C                 -2.77532700    0.71329200    6.67369900
 H                 -3.89628500    0.90874500    4.84999000
 C                 -0.39486700    0.47635000    6.42130700
 H                  0.36107300    0.49309500    4.41845000
 C                 -1.51611100    0.55554100    7.25082400
 H                 -3.65957800    0.77865000    7.30259600
 H                  0.59400200    0.35792400    6.85708400
 H                 -1.40655500    0.49652200    8.33003200
 H                  0.62353100    1.18124900   -2.22021000
 C                 -0.40342700    0.87418600   -2.37501300
 C                 -1.54473100    0.56811900   -2.67459500
 C                 -2.85165700    0.23131600   -3.17114700
 C                 -3.09701700   -1.03449300   -3.72235200
 C                 -3.88242000    1.18095700   -3.13144400
 C                 -4.35974500   -1.34547600   -4.21805100
 H                 -2.29878500   -1.76865300   -3.76718900
 C                 -5.14142900    0.86428800   -3.63052300
 H                 -3.69105500    2.16018200   -2.70338500
 C                 -5.38311100   -0.39872100   -4.17183800
 H                 -4.54247900   -2.32696700   -4.64494500
 H                 -5.93516800    1.60420000   -3.59530500
 H                 -6.36710300   -0.64334300   -4.56076500

Ru
sdd
****
-C -H -O -P -Cl
6-31+g*
****

Ru
sdd





