%nprocshared=8
%mem=24000MB
#p wb97xd/genecp opt freq=noraman scrf=(solvent=toluene,smd) nosymm scf(conver=7,xqc,maxcycle=100)

Title Card Required

0 1
 Ru                -0.08459800    0.57880400    0.27036500
 H                 -0.44471800    0.28472600    1.80497000
 P                 -0.29757500    2.90840900    0.60928500
 C                 -1.15863800    3.43570500    2.13874600
 H                 -1.26198100    4.52515600    2.18438200
 H                 -2.15174600    2.97761700    2.17460600
 H                 -0.59060300    3.09121500    3.00839600
 C                  1.26056300    3.87275400    0.67606700
 H                  1.83222800    3.70382800   -0.24141100
 H                  1.04546600    4.94167600    0.77785700
 H                  1.86827200    3.54679100    1.52533900
 C                 -1.23511300    3.76476000   -0.71203000
 H                 -2.25318500    3.36603700   -0.75922700
 H                 -1.27968300    4.84425100   -0.53236500
 H                 -0.74680700    3.56997200   -1.67098900
 C                 -1.93728500    0.43029600    0.09233700
 O                 -3.08969000    0.33262600    0.07990900
 P                  0.17728700   -1.76137600    0.00648000
 C                  1.15102500   -2.30047400   -1.45017800
 H                  0.64390300   -1.96344700   -2.35809900
 H                  2.14862600   -1.85280100   -1.41655000
 H                  1.25004000   -3.39119200   -1.47186500
 C                 -1.35816000   -2.74290300   -0.15945600
 H                 -1.13433300   -3.80686700   -0.29018400
 H                 -1.97742500   -2.61320800    0.73333600
 H                 -1.91084600   -2.37423700   -1.02822600
 C                  1.04456200   -2.58718800    1.39595300
 H                  0.47290100   -2.44087800    2.31720100
 H                  1.16222800   -3.65967800    1.20720600
 H                  2.03210700   -2.13602100    1.53155400
 C                  1.77115600    0.98806700    5.12189800
 C                  1.35337700    0.83470100    3.80157100
 C                  2.28662500    0.84843700    2.75998200
 C                  3.64903300    1.01738300    3.06564600
 C                  4.06086100    1.16973100    4.38498800
 C                  3.12239400    1.15646000    5.41863300
 H                  1.03455400    0.97598500    5.91983400
 H                  0.30259700    0.70222600    3.57002200
 H                  4.37786300    1.02994500    2.26053400
 H                  5.11605700    1.30122800    4.60586700
 H                  3.44424200    1.27766000    6.44884600
 C                  1.93659000    0.71285900    1.36075100
 C                  2.15372500    0.67282100    0.14230300
 H                  2.58514000    0.68382900   -0.83938500
 O                  0.29460500    1.04581500   -1.88504500
 C                 -0.43899700    0.56605400   -2.81775500
 C                 -0.05168900    0.98224200   -4.23228200
 H                 -0.94668900    1.23994500   -4.80628800
 H                  0.64557700    1.82323700   -4.23223400
 H                  0.42543500    0.13091200   -4.73197800
 O                 -1.39700300   -0.21323700   -2.65942900

Ru
sdd
****
-C -H -O -P -Cl
6-31+g*
****

Ru
sdd





