%nprocshared=8
%mem=24000MB
#p wb97xd/genecp opt freq=noraman scrf=(solvent=toluene,smd) nosymm scf(conver=7,xqc,maxcycle=100)

Title Card Required

0 1
 Ru                 0.01464300    0.64900800    0.06582400
 H                 -0.67042000    0.56494500    1.50064100
 P                 -0.20698800    3.00714800    0.19536300
 C                 -0.36883500    3.66881600    1.89698800
 H                 -0.43883900    4.76184600    1.89407500
 H                 -1.26419300    3.24841700    2.36428200
 H                  0.50017000    3.36465200    2.48874800
 C                  1.19998600    3.96751000   -0.47945900
 H                  1.35430400    3.68773800   -1.52546400
 H                  1.00571600    5.04297300   -0.40989200
 H                  2.10980600    3.73244800    0.08073200
 C                 -1.64148000    3.74623300   -0.67260900
 H                 -2.57216300    3.34764000   -0.25777100
 H                 -1.64279000    4.83652600   -0.56989100
 H                 -1.59442200    3.48391100   -1.73400900
 C                 -1.74860600    0.44489000   -0.50717600
 O                 -2.85316000    0.31990700   -0.82598700
 Cl                 0.77978800    0.74908000   -2.40445300
 P                  0.34972400   -1.69851800    0.06646600
 C                 -0.63591400   -2.63400700   -1.16119200
 H                 -1.70223700   -2.52757600   -0.94034200
 H                 -0.44555700   -2.21782700   -2.15500900
 H                 -0.37330300   -3.69699100   -1.15192200
 C                 -0.00972900   -2.56651700    1.64031900
 H                  0.16824400   -3.64346600    1.54920500
 H                  0.62907500   -2.16132500    2.43115900
 H                 -1.05342400   -2.39373700    1.91988000
 C                  2.06165400   -2.23218200   -0.30907700
 H                  2.74388600   -1.86808800    0.46417500
 H                  2.12494700   -3.32426400   -0.35986700
 H                  2.36304600   -1.80303700   -1.26934700
 C                  0.84769300    0.32507100    5.21829500
 C                  0.69486100    0.41985000    3.83690200
 C                  1.79809300    0.69205300    3.02143800
 C                  3.05928000    0.87126000    3.61745100
 C                  3.20646300    0.77751600    4.99693100
 C                  2.10024300    0.50264300    5.80317800
 H                 -0.01816200    0.11038400    5.83785200
 H                 -0.28013100    0.28058500    3.38323200
 H                  3.91907000    1.08496400    2.98908000
 H                  4.18620700    0.91870600    5.44378200
 H                  2.21631000    0.42651400    6.88026600
 C                  1.73324500    0.80023800    1.57661900
 C                  2.20599200    0.95577800    0.44058600
 H                  2.86406300    1.10703700   -0.39296400

Ru
sdd
****
-C -H -O -P -Cl
6-31+g*
****

Ru
sdd





