%nprocshared=8
%mem=24000MB
#p wb97xd/genecp opt freq=noraman scrf=(solvent=toluene,smd) nosymm scf(conver=7,xqc,maxcycle=100)

Title Card Required

0 1
 Ru                -1.09362100    0.51954500   -0.18173500
 P                 -0.97038000    2.88236700   -0.03038800
 C                 -2.47149900    3.71573100    0.59632800
 H                 -2.29501100    4.78688100    0.73784800
 H                 -3.29414200    3.57818700   -0.11178500
 H                 -2.75271600    3.26180200    1.55113100
 C                  0.33872400    3.41996800    1.12800200
 H                  1.30158100    3.03231700    0.78351400
 H                  0.38183100    4.51220100    1.19336000
 H                  0.13069300    2.99793400    2.11551500
 C                 -0.57818100    3.78573800   -1.57389400
 H                 -1.35933500    3.59973700   -2.31678300
 H                 -0.50207000    4.86227300   -1.38805600
 H                  0.37086900    3.42339900   -1.97960800
 C                 -2.87946800    0.53096100   -0.51463000
 O                 -4.02217300    0.53807100   -0.73126700
 P                 -1.00528700   -1.84528700   -0.04411600
 C                 -2.50684600   -2.65577400    0.61140500
 H                 -2.75855900   -2.20161700    1.57431000
 H                 -3.34246500   -2.50017900   -0.07754200
 H                 -2.34597400   -3.73054600    0.74381400
 C                  0.31847700   -2.40912400    1.08462800
 H                  0.34386500   -3.50213000    1.14633100
 H                  1.28045000   -2.03717400    0.72100400
 H                  0.13854700   -1.98639600    2.07733700
 C                 -0.66172900   -2.74693600   -1.59978600
 H                  0.28350100   -2.39688700   -2.02448600
 H                 -0.59878100   -3.82547100   -1.42091400
 H                 -1.45613000   -2.54443900   -2.32404600
 O                  1.14411800    0.50939200   -0.28347800
 O                 -0.01450400    0.51760100   -2.13841300
 C                  1.11110400    0.51592000   -1.55464100
 C                  2.39025800    0.54233500   -2.34353500
 H                  3.08565500   -0.20816500   -1.95749600
 H                  2.19705400    0.36429200   -3.40261700
 H                  2.86353500    1.52330800   -2.22600600
 C                 -1.45435600    0.51512900    1.78039100
 C                 -1.61030200    0.50933500    2.99608400
 C                 -1.75754000    0.49877600    4.42218900
 C                 -0.63425000    0.61902700    5.26099500
 C                 -3.02469000    0.36529600    5.01809500
 C                 -0.77603100    0.60553000    6.64609200
 H                  0.35003800    0.72332000    4.81283300
 C                 -3.16109800    0.35241800    6.40390700
 H                 -3.90081700    0.27188600    4.38231000
 C                 -2.03884100    0.47169200    7.22520900
 H                  0.10454300    0.69892700    7.27610400
 H                 -4.14861800    0.24706500    6.84513700
 H                 -2.14805300    0.46052300    8.30597400

Ru
sdd
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-C -H -O -P -Cl
6-31+g*
****

Ru
sdd





