%nprocshared=8
%mem=24000MB
#p wb97xd/genecp opt freq=noraman scrf=(solvent=toluene,smd) nosymm scf(conver=7,xqc,maxcycle=100)

Title Card Required

0 1
 Ru                -1.06708400    0.52147900   -0.18021400
 P                 -0.95002700    2.89124600   -0.06516500
 C                 -2.51878400    3.73876000    0.34705500
 H                 -2.36109500    4.81443200    0.47520000
 H                 -3.25336300    3.57625200   -0.44730300
 H                 -2.91397600    3.31782500    1.27706100
 C                  0.19406100    3.50471600    1.22421900
 H                  1.19156900    3.09379600    1.04719900
 H                  0.23672900    4.59891800    1.21463200
 H                 -0.15637600    3.16391000    2.20331700
 C                 -0.38189600    3.74060700   -1.58531000
 H                 -1.08291500    3.54222200   -2.40166900
 H                 -0.31210700    4.82179000   -1.42575200
 H                  0.60158600    3.35267800   -1.86665600
 C                 -2.85814400    0.55768200   -0.46677800
 O                 -4.00338300    0.58124900   -0.68546200
 P                 -1.04798700   -1.85153900   -0.07962400
 C                 -2.64760000   -2.63261300    0.34525100
 H                 -3.01842300   -2.19575900    1.27790600
 H                 -3.38050500   -2.44002100   -0.44386600
 H                 -2.53273900   -3.71379300    0.47231200
 C                  0.08247700   -2.52356600    1.19290800
 H                  0.07423300   -3.61842000    1.17721400
 H                  1.09605500   -2.15924600    1.00593300
 H                 -0.23969100   -2.17369300    2.17848700
 C                 -0.53557900   -2.71831200   -1.61024900
 H                  0.47185100   -2.39414300   -1.88756900
 H                 -0.53836000   -3.80366000   -1.46358900
 H                 -1.22119400   -2.46430600   -2.42422200
 C                 -1.30943000    0.51624800    1.79907000
 C                 -2.38474000    0.53214700    2.60538100
 H                 -0.31533200    0.49490500    2.26343300
 C                 -2.37171300    0.51285500    4.08284300
 H                 -3.38217500    0.57398400    2.16563000
 C                 -3.57828300    0.70895100    4.77388800
 C                 -1.21093200    0.29933000    4.84690800
 C                 -3.62767900    0.70433800    6.16698400
 H                 -4.49305800    0.87034300    4.20714200
 C                 -1.25736000    0.29642800    6.23808600
 H                 -0.25857700    0.12663600    4.35296100
 C                 -2.46534200    0.49948300    6.90896500
 H                 -4.57743200    0.86042300    6.67177900
 H                 -0.34356000    0.12844600    6.80215400
 H                 -2.49892900    0.49346000    7.99481500
 Cl                 1.41199400    0.47774500   -0.34965800

Ru
sdd
****
-C -H -O -P -Cl
6-31+g*
****

Ru
sdd





