%nprocshared=8
%mem=24000MB
#p wb97xd/genecp scrf=(solvent=toluene,smd) nosymm scf(xqc,maxcycle=150)

Title Card Required

0 1
 C                 -2.79427600    0.93553900   -2.44726100
 C                 -2.26034800    1.01563800   -3.55405300
 C                 -1.75195100    1.10007600   -4.89548600
 C                 -0.78679700    0.19257200   -5.36178200
 C                 -2.21594100    2.09769000   -5.76938600
 C                 -0.29998500    0.28276600   -6.66232700
 H                 -0.41837900   -0.57875700   -4.69080000
 C                 -1.72839700    2.18286400   -7.06984400
 H                 -2.96261600    2.80370600   -5.41622000
 C                 -0.76827200    1.27697300   -7.52143200
 H                  0.44904500   -0.42536000   -7.00633400
 H                 -2.09733800    2.96016600   -7.73383100
 H                 -0.38482500    1.34785800   -8.53557400
 P                 -4.72987400    2.96330000   -1.00493100
 C                 -4.90935500    3.52046100   -2.77467900
 H                 -3.87258600    3.48210100   -3.12882900
 C                 -6.26913800    3.39361400   -0.03738000
 H                 -6.08133000    2.88102100    0.91317300
 C                 -3.45031100    4.13372400   -0.30163800
 H                 -3.85459100    5.14553000   -0.42371900
 C                 -5.41206000   -0.00024500   -1.48859500
 O                 -6.36071300   -0.46530400   -1.98464500
 P                 -2.94835400   -1.42619600   -0.32584400
 C                 -2.41206300   -2.32305100   -1.87030200
 H                 -1.67373700   -1.62656000   -2.28424900
 C                 -3.90315400   -2.58595500    0.78248900
 H                 -4.29836200   -1.89784200    1.53777700
 C                 -1.35615000   -1.15854600    0.61281200
 H                 -0.93204800   -2.15260100    0.79670900
 C                 -4.84055900    0.65527700    1.15563000
 C                 -5.96992600    0.13290400    1.67094100
 H                 -4.20072000    1.16892300    1.89369200
 C                 -6.40538100    0.17884700    3.08270200
 H                 -6.64628900   -0.42520500    1.01918200
 C                 -7.39798000   -0.71168400    3.52295600
 C                 -5.87667100    1.07761400    4.02478000
 C                 -7.83097300   -0.72139700    4.84706300
 H                 -7.83005000   -1.41259500    2.81090400
 C                 -6.30619300    1.06974900    5.34854700
 H                 -5.12583700    1.80133100    3.71738800
 C                 -7.28528100    0.16893800    5.77073700
 H                 -8.59728300   -1.42709400    5.15790100
 H                 -5.88128700    1.77895900    6.05489200
 H                 -7.62202700    0.16673400    6.80386900
 C                 -7.52298100    2.75044500   -0.63765300
 H                 -7.38157300    1.68934400   -0.85911100
 H                 -8.34728900    2.82663900    0.08151000
 H                 -7.83694900    3.25888300   -1.55610200
 C                 -6.52199100    4.87358900    0.27259600
 H                 -6.77773000    5.45222800   -0.61960700
 H                 -7.37195500    4.94530400    0.96282600
 H                 -5.67363900    5.36194800    0.76145500
 C                 -2.10817400    4.06478200   -1.03448000
 H                 -1.64148900    3.08210700   -0.91561600
 H                 -2.19112700    4.26406700   -2.10669900
 H                 -1.41980900    4.80773900   -0.61354700
 C                 -3.23416000    3.87692700    1.19507200
 H                 -2.74398600    2.91019200    1.36198100
 H                 -2.57612900    4.64931500    1.61090800
 H                 -4.16321500    3.88349500    1.77365500
 C                 -5.43166500    4.94806500   -2.96178300
 H                 -4.92028200    5.68048000   -2.32840100
 H                 -5.27857700    5.25478000   -4.00393900
 H                 -6.50637100    5.01093300   -2.76035600
 C                 -5.69604700    2.53260000   -3.64367100
 H                 -6.73013800    2.40792000   -3.30836600
 H                 -5.72919200    2.90869100   -4.67408600
 H                 -5.21688300    1.55116500   -3.66775800
 C                 -5.11089400   -3.20228000    0.06873200
 H                 -5.78349400   -3.64784400    0.81183500
 H                 -5.68970600   -2.46636600   -0.49600200
 H                 -4.80773100   -3.99867100   -0.62017700
 C                 -3.10259500   -3.67056900    1.51276200
 H                 -2.30449800   -3.26209400    2.13994500
 H                 -3.78129300   -4.21907900    2.17795100
 H                 -2.65851600   -4.39882600    0.82819800
 C                 -1.73402700   -3.67837800   -1.64759400
 H                 -1.26786300   -4.00796500   -2.58451800
 H                 -0.94812300   -3.65055800   -0.88551900
 H                 -2.46162900   -4.44566200   -1.36183700
 C                 -3.52099200   -2.44248600   -2.92240500
 H                 -3.94368000   -1.46846200   -3.17730400
 H                 -3.09551200   -2.86372000   -3.84193000
 H                 -4.33195300   -3.10366600   -2.60238300
 C                 -1.61953700   -0.48760400    1.96771400
 H                 -1.89260600    0.56671700    1.83952200
 H                 -2.41912400   -0.96488600    2.54293200
 H                 -0.70660000   -0.51363100    2.57468200
 C                 -0.33410200   -0.34377900   -0.18362800
 H                 -0.71359000    0.65809100   -0.41052200
 H                  0.58373600   -0.22319100    0.40445700
 H                 -0.05675100   -0.81447000   -1.13138700
 Ru                -3.97455500    0.70501500   -0.72582600
 Cl                 0.75133100    2.24740200   -2.53390000
 H                 -0.47050000    1.77898300   -2.65790100

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-C -H -O -P -Cl
6-311++g**
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