%nprocshared=8
%mem=24000MB
#p wb97xd/genecp scrf=(solvent=toluene,smd) nosymm scf(xqc,maxcycle=150)

Title Card Required

0 1
 Ru                -1.16139100    0.09450500   -0.59038300
 P                 -0.31679200    2.32818100   -0.96391000
 C                 -1.17064700    3.67809300    0.02391600
 H                 -2.19337400    3.29916900    0.13145900
 C                  1.52847500    2.55223500   -0.83869300
 H                  1.88604200    1.88336900   -1.62975900
 C                 -0.69851100    2.79152900   -2.73599000
 H                 -0.47428000    3.85879600   -2.84459000
 C                 -2.77806100    0.79002900   -0.16250000
 O                 -3.81267600    1.25553500    0.10966700
 P                 -2.02092200   -2.16485700   -0.53802000
 C                 -1.75468200   -2.88856100   -2.23659400
 H                 -0.66297000   -2.98706500   -2.25975800
 C                 -3.84403700   -2.24303600   -0.11436500
 H                 -3.91630300   -1.57001300    0.75027500
 C                 -1.28157600   -3.44138000    0.60448800
 H                 -1.85235400   -4.35610500    0.40104800
 C                 -0.66273400    0.06442100    1.32884300
 C                 -1.24024400    0.49878700    2.46157900
 H                  0.31433300   -0.42573200    1.40128800
 C                 -0.66674700    0.39853900    3.81682400
 H                 -2.20851200    0.99823700    2.41803500
 C                 -1.34059100    1.00779300    4.88832100
 C                  0.53643200   -0.27023300    4.10439900
 C                 -0.83720300    0.96011700    6.18642300
 H                 -2.27510200    1.53116000    4.69494700
 C                  1.04036100   -0.31953500    5.40008100
 H                  1.09204900   -0.75726400    3.30746800
 C                  0.35896900    0.29576700    6.45163800
 H                 -1.38161800    1.44495800    6.99302800
 H                  1.97440000   -0.84260200    5.58995000
 H                  0.75647800    0.25626500    7.46211400
 C                 -4.71991000   -1.66151700   -1.23254700
 H                 -5.71334800   -1.42555200   -0.83393600
 H                 -4.31488800   -0.74249400   -1.66584400
 H                 -4.85256200   -2.38791500   -2.04190900
 C                 -4.39752000   -3.60746200    0.31657000
 H                 -3.91982200   -3.99531100    1.22036500
 H                 -5.46691600   -3.50086700    0.53787000
 H                 -4.30176300   -4.36268300   -0.46998500
 C                 -2.11404400   -1.90024100   -3.35414800
 H                 -1.68434400   -2.24794100   -4.30137600
 H                 -3.19395300   -1.80108000   -3.49636300
 H                 -1.70030700   -0.90151900   -3.16687800
 C                 -2.37246100   -4.26396300   -2.49746200
 H                 -3.46438400   -4.21158400   -2.56592200
 H                 -2.00400800   -4.65463600   -3.45460200
 H                 -2.11198800   -4.99664900   -1.72660900
 C                 -1.46901700   -3.08423800    2.08554700
 H                 -1.31442200   -3.98264300    2.69547300
 H                 -0.73995700   -2.33623600    2.40477000
 H                 -2.46069700   -2.68600300    2.32170800
 C                  0.19317400   -3.73762100    0.32027000
 H                  0.80898400   -2.83857700    0.41493600
 H                  0.55415500   -4.47957300    1.04382500
 H                  0.35690800   -4.14831500   -0.68120300
 C                 -1.26759600    5.05669600   -0.64184900
 H                 -1.82704600    5.03898700   -1.58195900
 H                 -1.80014400    5.73647300    0.03506300
 H                 -0.28401800    5.49515800   -0.83736900
 C                 -0.59174600    3.81798900    1.43744500
 H                 -1.27120500    4.42436500    2.04910300
 H                 -0.46576800    2.85391700    1.93520000
 H                  0.37616800    4.32979800    1.42143800
 C                  2.12914200    2.01914900    0.46615100
 H                  1.87923600    0.96677000    0.61508100
 H                  3.22252800    2.09243900    0.40708700
 H                  1.80692000    2.58088200    1.34700000
 C                  2.02538700    3.96887200   -1.14313200
 H                  3.11693600    3.95215600   -1.25343500
 H                  1.61084700    4.37647800   -2.07147600
 H                  1.79112500    4.66452700   -0.33034600
 C                 -2.19064800    2.58138000   -3.02616000
 H                 -2.44234100    3.00575800   -4.00561700
 H                 -2.44057400    1.51327100   -3.05745200
 H                 -2.84409100    3.05133800   -2.28327400
 C                  0.15278800    2.02989200   -3.75636100
 H                  0.06153900    0.94521600   -3.63862200
 H                 -0.17632700    2.29197300   -4.76979000
 H                  1.21602100    2.27946700   -3.68343200
 Cl                 0.95787400   -0.80190300   -1.54153000

Ru
sdd
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-C -H -O -P -Cl
6-311++g**
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Ru
sdd







