%nprocshared=8
%mem=24000MB
#p wb97xd/genecp scrf=(solvent=toluene,smd) nosymm scf(xqc,maxcycle=150)

Title Card Required

0 1
 O                  1.74516500    0.42256600    0.68988100
 O                  2.34095300    1.55006500    2.52900700
 C                  2.59237300    1.01803500    1.32282900
 C                  4.00101500    1.25741900    0.87456800
 H                  4.15899100    0.80621000   -0.10512000
 H                  4.19392500    2.33401800    0.82340700
 H                  4.70257700    0.83290600    1.60013300
 H                  1.40879400    1.37554700    2.75207000
 C                 -0.57552000    0.22448600   -2.25359200
 C                 -0.06679500    0.10036800   -3.36399700
 C                  0.55801600   -0.05007600   -4.64150500
 C                 -0.14905000    0.20273100   -5.83094200
 C                  1.90172200   -0.45743100   -4.73528200
 C                  0.46850000    0.05065900   -7.06905300
 H                 -1.18772000    0.51659100   -5.77002500
 C                  2.51315000   -0.60784000   -5.97626100
 H                  2.45597000   -0.65428700   -3.82131100
 C                  1.80139300   -0.35436700   -7.14945400
 H                 -0.09395600    0.25044700   -7.97757400
 H                  3.55220800   -0.92334700   -6.02843500
 H                  2.28108900   -0.47221900   -8.11724700
 P                 -1.12581900    2.66326600   -0.24894100
 C                 -1.80403200    3.50264000    1.27684900
 H                 -1.82436100    4.57301800    1.04495600
 C                  0.60976800    3.36424200   -0.33129200
 H                  1.02883300    3.01631900    0.62040100
 C                 -2.15184200    3.45175800   -1.62092800
 H                 -3.00778900    2.77170500   -1.70647900
 C                 -3.01432700    0.38220500   -0.48609900
 O                 -4.16759100    0.51198300   -0.62460600
 P                 -1.32445100   -2.17858000   -0.50210200
 C                 -1.80712600   -2.76408300   -2.20880100
 H                 -0.96306100   -2.42054200   -2.81620900
 C                 -2.37930700   -3.07034000    0.76035700
 H                 -2.11553500   -2.54147700    1.68186200
 C                  0.35718800   -2.95102100   -0.24243600
 H                  0.21463900   -4.02586600   -0.40705400
 C                 -1.34119300   -0.00465300    1.75991200
 C                 -2.26810700   -0.22838000    2.71006500
 H                 -0.30348000   -0.02179600    2.13047400
 C                 -2.00346100   -0.46837000    4.14349700
 H                 -3.32837300   -0.21578400    2.44541300
 C                 -3.02124700   -0.24749200    5.08592100
 C                 -0.76420500   -0.92740700    4.62355300
 C                 -2.80699600   -0.44881700    6.44749700
 H                 -3.99335500    0.09797500    4.73877400
 C                 -0.54629500   -1.12659300    5.98381300
 H                  0.03413300   -1.15367600    3.92022300
 C                 -1.56519200   -0.88667100    6.90697700
 H                 -3.61299700   -0.26280800    7.15305700
 H                  0.42123300   -1.48716500    6.32519700
 H                 -1.39564100   -1.04800500    7.96799800
 C                  0.69042800    4.89587000   -0.33304500
 H                  1.73851300    5.20053200   -0.21802000
 H                  0.33322500    5.31525300   -1.27896700
 H                  0.12622800    5.36037200    0.48175400
 C                  1.49343900    2.78507100   -1.44226900
 H                  2.53180400    3.09748900   -1.26853400
 H                  1.46380300    1.69542200   -1.47065400
 H                  1.20408000    3.15017500   -2.43095500
 C                 -1.44004200    3.45169300   -2.97981100
 H                 -0.97991000    2.48922400   -3.20964900
 H                 -2.17239700    3.67295700   -3.76601400
 H                 -0.67103800    4.23067300   -3.02443600
 C                 -2.70476800    4.85636400   -1.33968000
 H                 -3.38513200    4.89287100   -0.48462900
 H                 -1.90980700    5.59122700   -1.17602000
 H                 -3.27579600    5.18617900   -2.21667200
 C                 -0.92601900    3.31808600    2.51848500
 H                 -0.79148100    2.25788500    2.75214600
 H                  0.05458300    3.79497700    2.41532100
 H                 -1.41856500    3.77734500    3.38453300
 C                 -3.24070800    3.05149900    1.56449200
 H                 -3.88743700    3.08194000    0.68162700
 H                 -3.25172500    2.03083000    1.95214200
 H                 -3.68572900    3.70735700    2.32339000
 C                 -3.87862800   -2.84765600    0.53676700
 H                 -4.42879900   -3.16522600    1.43107300
 H                 -4.13021000   -1.80064300    0.35353100
 H                 -4.25177600   -3.44100400   -0.30546500
 C                 -2.10527400   -4.56315800    0.98852400
 H                 -1.05579300   -4.78617100    1.20013200
 H                 -2.68263400   -4.89143600    1.86227200
 H                 -2.41698500   -5.18156200    0.14237800
 C                 -1.93170100   -4.28201700   -2.37467400
 H                 -1.97546400   -4.52153700   -3.44446400
 H                 -1.08645200   -4.83489200   -1.95201000
 H                 -2.85279400   -4.66217600   -1.92011100
 C                 -3.04916300   -2.06243600   -2.76958100
 H                 -2.91684400   -0.97925300   -2.80349100
 H                 -3.21470600   -2.40469600   -3.79912000
 H                 -3.95526300   -2.28788200   -2.19860200
 C                  0.85392600   -2.74327300    1.19400900
 H                  1.09503300   -1.69183000    1.36898900
 H                  0.12917600   -3.05711100    1.95145000
 H                  1.77061700   -3.32611900    1.35002000
 C                  1.40737600   -2.45546200   -1.24172700
 H                  2.35445900   -2.97815800   -1.05392300
 H                  1.12550300   -2.64863400   -2.28132500
 H                  1.58623500   -1.38221600   -1.13219100
 Ru                -1.25949200    0.23478700   -0.29025900

Ru
sdd
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-C -H -O -P -Cl
6-311++g**
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Ru
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