%mem=185GB
%nprocshared=36
%chk=TMPH_thf.chk
#p opt freq b3lyp/gen scrf=(solvent=thf,pcm) empiricaldispersion=gd3bj

TMPH_thf

0 1
 C                 -1.33592000   -0.26116500    0.00003200
 C                 -1.33941100    1.29293300   -0.00019700
 C                  0.00000400    2.07002200   -0.00004100
 C                  1.33941700    1.29292600    0.00124900
 C                  1.33592300   -0.26116600    0.00004200
 N                 -0.00000200   -0.83557700    0.00007200
 H                  0.00046400    2.73226900   -0.86800000
 H                 -1.91611100    1.61779900   -0.86808100
 H                  1.91737200    1.61849600   -0.86553400
 H                 -0.00000300   -1.84413100   -0.00054800
 H                 -0.00044600    2.73327500    0.86714600
 H                  1.91522100    1.61733600    0.86990100
 H                 -1.91647400    1.61804300    0.86735400
 C                 -2.08899800   -0.76395200   -1.25224400
 H                 -2.10298300   -1.85836500   -1.27602300
 H                 -3.12553500   -0.41120900   -1.26420300
 H                 -1.58751800   -0.40980900   -2.15651800
 C                 -2.08901000   -0.76359100    1.25244500
 H                 -3.12557600   -0.41092300    1.26424000
 H                 -2.10288700   -1.85799400    1.27660100
 H                 -1.58760700   -0.40908300    2.15662000
 C                  2.08863000   -0.76283800   -1.25291700
 H                  3.12514200   -0.41002100   -1.26492300
 H                  2.10265700   -1.85722600   -1.27764000
 H                  1.58683800   -0.40794700   -2.15672900
 C                  2.08936700   -0.76471000    1.25178100
 H                  2.10345600   -1.85913800    1.27483100
 H                  3.12588100   -0.41188800    1.26368400
 H                  1.58810600   -0.41120000    2.15641800

C H N 
6-31G(d)
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