%nprocshared=20
%mem=20000MB
%chk=IE19_TS1-2a_S1S13_CF3.chk
#p opt=(calcfc,ts,noeigentest) freq=noraman genecp
scrf=(solvent=chlorobenzene,pcm) nosymm # bp86 empiricaldispersion=gd3
gfinput gfprint scf=maxcyc=100

opt freq

1 1
 Au                -2.27495100    7.41325900    7.74471700
 C                 -5.68137100    7.64771100    8.78314400
 C                 -6.62459300    7.69382200    9.83795900
 C                 -7.96522400    7.33285900    9.65322400
 C                 -8.40244600    6.92580100    8.38491200
 C                 -7.48918900    6.88859400    7.32417500
 C                 -6.12849200    7.23579800    7.49111900
 C                 -5.27969500    7.20412800    6.26502400
 C                 -4.28993500    6.22175800    6.04498500
 C                 -3.48342200    6.24945300    4.89618200
 C                 -3.60931800    7.29242400    3.94198800
 C                 -4.68137500    8.20772300    4.10787500
 C                 -5.49320700    8.15207500    5.24413200
 C                 -2.75008700    8.53840600    1.93917700
 C                 -1.59146000    8.19092500    0.97431000
 C                 -0.53737400    7.59759500    1.92260000
 C                 -1.38902100    6.75657000    2.91498300
 C                 -2.55301600    9.90388900    2.60814400
 C                 -2.94237000   11.07399600    1.93562700
 C                 -2.76344900   12.33294000    2.53426600
 C                 -2.19915700   12.44371700    3.81307500
 C                 -1.81005000   11.27319700    4.48230300
 C                 -1.98282200   10.01501700    3.88838900
 C                 -3.26166600   13.56841000    1.81893400
 C                 -1.15927200   11.38315100    5.83803900
 C                 -1.43407200    5.27338600    2.54983000
 C                 -0.30965200    4.46695200    2.80911900
 C                 -0.33346400    3.09639800    2.51442100
 C                 -1.47327700    2.50768800    1.94388900
 C                 -2.58544600    3.31590000    1.67086500
 C                 -2.57112200    4.68813100    1.97370000
 C                  0.84968200    2.23734000    2.89223200
 C                 -3.85241600    2.70531500    1.11561600
 C                 -3.43827100    7.66932100   10.88902900
 C                 -4.08700900   10.16272500    8.97710200
 P                 -3.96323000    8.26249600    9.12680200
 N                 -2.70953800    7.41019700    2.88330500
 F                 -3.08250400   13.47473100    0.47047400
 F                 -2.62785700   14.69639800    2.24453100
 F                 -4.59877400   13.75333700    2.03024200
 F                 -1.18845700   10.18695600    6.51081600
 F                 -1.77783800   12.30620500    6.62899300
 F                  0.15015900   11.74996100    5.74700600
 F                  0.71518700    1.76114600    4.17537100
 F                  2.01930800    2.93424400    2.85622000
 F                  0.97982100    1.15378000    2.08300200
 F                 -4.75608200    2.46526500    2.11241500
 F                 -4.46006500    3.53771100    0.22250400
 F                 -3.62006300    1.52042300    0.48706700
 H                 -3.71766100    8.54145900    1.40317700
 H                 -1.23265100    9.07057300    0.41688100
 H                 -1.93670100    7.43101400    0.25110400
 H                 -0.01805900    8.40246900    2.47243700
 H                  0.22145800    6.98795000    1.40754100
 H                 -0.96545400    6.84144500    3.93950500
 H                 -6.31631800    8.03237900   10.82780800
 H                 -9.44723200    6.64259800    8.21967500
 H                 -7.82024800    6.57789000    6.32735500
 H                 -4.17969700    5.39357300    6.75555500
 H                 -2.75798200    5.44910900    4.74695600
 H                 -6.29690900    8.88773200    5.35664600
 H                 -4.86379800    8.99195400    3.36949900
 H                 -3.39144200   11.00827000    0.93889600
 H                 -1.70401300    9.11569200    4.44266900
 H                 -2.07122300   13.42324900    4.28041200
 H                 -1.48941000    1.44092800    1.70931600
 H                 -3.44889900    5.30903500    1.77238700
 H                  0.59835900    4.90400100    3.23801400
 C                 -0.57862600    6.42357600    6.95554300
 C                  0.39431800    7.24341000    7.14492800
 C                 -2.73487000   10.77977400    9.39399100
 H                 -2.55344700   10.68183800   10.47735400
 H                 -1.88915900   10.32964400    8.84755700
 H                 -2.74669600   11.85809100    9.15312200
 C                 -5.23716500   10.76369300    9.81258500
 H                 -6.21343000   10.33079200    9.53650900
 H                 -5.09165000   10.63987900   10.89670500
 H                 -5.28235100   11.84941200    9.60604000
 C                 -4.36496000   10.44858800    7.48238600
 H                 -3.62950300    9.96997000    6.81553300
 H                 -5.36964000   10.10105100    7.19206000
 H                 -4.31752400   11.53967500    7.31390800
 C                 -1.88981000    7.74707000   10.98111500
 H                 -1.40061700    7.03704800   10.29123300
 H                 -1.49865600    8.75461000   10.76716400
 H                 -1.58899200    7.47946100   12.01150200
 C                 -4.00811500    8.48338200   12.07281700
 H                 -3.69078500    7.99200800   13.01130300
 H                 -3.60961300    9.51132700   12.09196500
 H                 -5.10689400    8.53979400   12.09808900
 C                 -3.85309300    6.18252500   10.98932600
 H                 -3.40052000    5.74807400   11.89994800
 H                 -4.94480400    6.04817800   11.05315400
 H                 -3.48361200    5.60620700   10.12011900
 C                 -0.57736500    5.04767000    6.34402200
 H                 -0.76419500    5.15339400    5.26096600
 H                 -1.41656200    4.44859200    6.73447300
 C                  0.76175700    4.31089700    6.59977800
 H                  0.82007100    3.46252600    5.89039300
 H                  0.74645900    3.87043400    7.61262300
 Br                 1.32758600    8.61498800    7.86138600
 C                  2.06853700    6.17511600    5.53162900
 H                  2.95591900    6.81191100    5.45516400
 H                  1.28337700    6.35310000    4.78927900
 C                  1.99369500    5.17776600    6.45668100
 C                  3.11699900    4.91504300    7.42563700
 H                  4.00097000    5.54114200    7.22265700
 H                  2.78015600    5.10406800    8.46300800
 H                  3.42174700    3.85210500    7.38308400
 C                 -8.94285035    7.39832096   10.84131552
 F                 -8.28965650    7.08163413   11.97953661
 F                 -9.44446355    8.64753695   10.94301894
 F                 -9.95144070    6.52317723   10.64289941

