%nprocshared=20
%mem=41GB
%chk=pcl3
#p opt freq=noraman b3lyp 6-31+G(d,p) nosymm empiricaldispersion=gd3 scf=(maxcycle=1024,xqc)

opt freq

0 1
 P                  0.00000031    0.00000000   -0.52545460
 Cl                 0.96166493   -1.66565333    0.15454550
 Cl                -1.92333013    0.00000000    0.15454541
 Cl                 0.96166493    1.66565333    0.15454550


--link1--
%nprocshared=20
%mem=41GB
%chk=pcl3
#p nmr geom=checkpoint guess=read pbe1pbe gen nosymm empiricaldispersion=gd3 scf=(maxcycle=1024,xqc)

nmr

0 1

Cl 0
6-31G*
****
P     0
S    11   1.00
      0.866084D+06           0.234863D-04
      0.129724D+06           0.182550D-03
      0.295299D+05           0.958818D-03
      0.836806D+04           0.403315D-02
      0.273130D+04           0.145229D-01
      0.986418D+03           0.458816D-01
      0.384999D+03           0.125730D+00
      0.158950D+03           0.287691D+00
      0.688257D+02           0.488132D+00
      0.307827D+02           0.500000D+00
      0.137974D+02           0.201500D+00
S    5   1.00
      0.233239D+03          -0.518782D-02
      0.731494D+02          -0.387465D-01
      0.278301D+02          -0.105629D+00
      0.558310D+01           0.331375D+00
      0.250585D+01           0.500000D+00
S    2   1.00
      0.353206D+01           0.180143D+00
      0.124707D+01           0.500000D+00
S    1   1.00
      0.665884D+00           1.0000000
S    1   1.00
      0.251973D+00           1.0000000
S    1   1.00
      0.966409D-01           1.0000000
P    6   1.00
      0.183416D+05           0.369307D-04
      0.282179D+04           0.750121D-03
      0.668877D+03           0.686309D-02
      0.216902D+03           0.381426D-01
      0.814129D+02           0.163988D+00
      0.339977D+02           0.500000D+00
P    1   1.00
      0.152309D+02           1.0000000
P    1   1.00
      0.705993D+01           1.0000000
P    1   1.00
      0.331474D+01           1.0000000
P    1   1.00
      0.153501D+01           1.0000000
P    1   1.00
      0.667849D+00           1.0000000
P    1   1.00
      0.300404D+00           1.0000000
P    1   1.00
      0.128611D+00           1.0000000
P    1   1.00
      0.511801D-01           1.0000000
D    1   1.00
      0.771000D+01           1.0000000
D    1   1.00
      0.203000D+01           1.0000000
D    1   1.00
      0.600000D+00           1.0000000
D    1   1.00
      0.220000D+00           1.0000000
F    1   1.00
      0.134000D+01           1.0000000
F    1   1.00
      0.450000D+00           1.0000000
G    1   1.00
      0.720000D+00           1.0000000
****