%chk=Ta6_TZ_opt.chk
%mem=20GB
%nprocshared=16
#p opt freq=noraman scrf=pcm nosymm geom=connectivity bp86/def2tzvp

geometry connectivity

-8 1
 Ta                 3.19033700    7.43948500    5.99056800
 Ta                 0.41532500    9.37253600    6.19914300
 Ta                 2.66469300    9.35311100    8.73898100
 O                  3.51124700    5.66518100    5.69643600
 O                  5.05392300    8.18215300    6.20739200
 O                  3.02916600    7.51531300    7.99557200
 O                  1.18209600    7.52854900    5.89929400
 O                  3.22799500    8.20065500    4.12383600
 O                  0.92838500    9.77254100    4.28679300
 O                  0.75127600    9.08494600    8.16055300
 O                  2.58042900    9.03725700   10.53670400
 O                 -1.38436100    9.07869900    6.07653300
 O                  2.77352800    9.76706500    6.37789800
 Ta                 2.35664100   12.09426600    6.76721600
 Ta                 5.13169600   10.16109500    6.55859000
 Ta                 2.88224500   10.18024200    4.02079500
 O                  2.03561800   13.86835600    7.06247300
 O                  0.49314900   11.35155400    6.55039800
 O                  2.51772200   12.01955200    4.76214100
 O                  4.36492000   12.00502900    6.85871600
 O                  2.31928500   11.33207400    8.63354500
 O                  4.61771800    9.76073000    8.47063900
 O                  4.79693200   10.44903400    4.59673900
 O                  2.96561300   10.49592900    2.22287000
 O                  6.93127500   10.45461500    6.68267500

 1 4 1.0 5 1.0 6 1.0 7 1.0 8 1.0 13 1.0
 2 7 1.0 9 1.0 10 1.0 12 1.0 18 1.0 13 1.0
 3 6 1.0 10 1.0 11 1.0 21 1.0 22 1.0 13 1.0
 4
 5 15 1.0
 6
 7
 8 16 1.0
 9 16 1.0
 10
 11
 12
 13 14 1.0 16 1.0 15 1.0
 14 17 1.0 18 1.0 19 1.0 20 1.0 21 1.0
 15 20 1.0 22 1.0 23 1.0 25 1.0
 16 19 1.0 23 1.0 24 1.0
 17
 18
 19
 20
 21
 22
 23
 24
 25

