%nprocshared=24
%mem=41GB
#p opt=(calcfc,maxstep=7) freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
  P          -0.11166566347148      0.27827353418187     -2.83807324467282
  Au          0.66408380002315      0.22281953115406     -0.64556430176684
  C          -1.81274273842387     -0.37507853622930     -2.97333106749213
  H          -2.49018645931910      0.22623898557813     -2.34323259903924
  H          -2.14381337991317     -0.32309670465578     -4.02628773574873
  H          -1.83434545726873     -1.42367746321777     -2.63092832770017
  C           0.90672561949839     -0.71494262698894     -3.98280561199066
  H           0.91666639279802     -1.76669291551001     -3.64868598608702
  H           0.48349882582216     -0.65407652866153     -5.00165814514956
  H           1.94010664610597     -0.32780625291846     -3.98798119513419
  C          -0.16145463131777      1.96681045610729     -3.53151877102836
  H           0.85551193200449      2.39536062747867     -3.53326491063311
  H          -0.54970694069219      1.93029962837534     -4.56538509607361
  H          -0.81913129222633      2.59998875184178     -2.91149028832525
  C           0.65482350908242     -0.09097453176012      1.74744179219441
  C           0.24851889635637     -1.50584257432185      2.15194567508353
  H           1.05007176233714     -2.02690517861895      2.69784488827972
  C           1.86907385368373      0.34807462878586      1.28219256077317
  H           2.11655238460121      1.41851188349632      1.31388246461322
  H           2.69812226794260     -0.35740904755266      1.13674690446828
  N          -1.64952733822710     -0.06055783896654      2.39081452540050
  C          -2.39010160276762     -0.31281428728345      1.16693419914870
  H          -3.24674094890057     -0.96855037194225      1.40066310114643
  H          -2.78105945702767      0.64476247913146      0.78457126056726
  H          -1.80152577562917     -0.79411751895920      0.35570005202411
  C          -0.97974801324348     -1.17638075933292      3.04128025071712
  H          -1.62862279997907     -2.01382662847481      3.32351318312053
  C          -0.12569004208163      0.72639932298021      3.86496720790917
  O           0.34469047394942      1.55064836163148      4.59386946029838
  O          -0.46121775800391     -0.53259283186450      4.24003549202535
  C          -0.45530974282731      0.79230720296234      2.35696457183253
  H          -0.57301936434965      1.80515057337612      1.95818993112820
  H          -0.05290008471320     -2.12902881008788      1.29365598989209

C H P N O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD






