%mem=3200mb
%nproc=4
#p B3LYP/genecp scf=(xqc,maxcyc=1000,conver=8)
freq 5D 7F scf=nosym empiricaldispersion=gd3

Bitartekari zentralaren dobletea base handiagoa erabiliz:

2 1
Si -2.22271068 0.07293744 0.49330574
H -2.31231069 -0.53165335 1.83902758
H -2.56642181 1.51618758 0.46339789
H -2.92181236 -0.70199015 -0.56017136
Rh 0.08884042 -0.00236487 -0.10117474
O 2.67970084 0.0147938 -0.01502092
O 0.70318909 0.81510615 1.70126657
O -0.00465722 1.9205501 -0.94728233
O 0.37721306 -1.85241542 0.80490588
O -0.36079058 -1.06654743 -1.86466839
H 3.11640487 -0.83301522 0.18823958
H 3.37590066 0.56276711 -0.42177263
H 1.68380224 0.86909902 1.62717304
H 0.37852781 1.69091813 1.9886925
H 0.58122874 2.15196899 -1.69299403
H -0.85185778 2.38485782 -1.09038048
H 0.20093612 -1.92313861 1.76440914
H -0.0072349 -2.641968 0.37537986
H -1.23046505 -1.01172567 -2.30598836
H 0.31823921 -1.14869541 -2.56192453

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


