%chk=Carbonate.chk%nprocshared=8%mem=22GB#p opt freq=noraman b97d3/6-311g** nosymm scrf=(smd,solvent=ButylAmine)Carbonate0 1 C                 -0.39958947    0.63903745    0.06720672 C                  1.12226853    0.63903745    0.06720672 C                  0.36330153    2.97647045   -0.06597928 H                 -0.79155147    0.03659245   -0.79030128 H                 -0.78970447    0.16862645    1.00471072 H                  1.51089553    0.10443945   -0.83607328 O                 -0.86879547    2.08335745   -0.03638328 O                  1.59104153    2.08690245    0.06720672 C                  1.66378630   -0.10534626    1.30181250 H                  1.31869174   -1.11806731    1.28746619 H                  2.73358129   -0.09281152    1.28503292 H                  1.31533504    0.37763864    2.19074855 O                  0.36674505    4.40054148   -0.19601708