%nprocshared=24
%mem=123GB
%chk=T4Syn_Si_Up_Cis_4.chk
#p freq=noraman
scrf=(smd,solvent=dichloroethane,read) nosymm pop=full geom=connectivity
def2svp empiricaldispersion=gd3 iop(6/80=1) rm062x scf=(maxcycle=250,xqc)

Title Card Required

0 1
 C                 -0.27886900    0.33722300   -0.60896100
 C                 -0.41308500    0.85762700    1.51757100
 N                  0.87804300    0.12046800    0.04015900
 N                  0.80002100    0.42519300    1.36042700
 N                 -1.09443400    0.85327500    0.33356700
 C                 -1.21021900    1.16013000    2.74782500
 H                 -0.70208300    0.73539500    3.62153600
 H                 -1.31554200    2.24710500    2.89627800
 O                 -2.45247700    0.50400600    2.61518100
 C                 -3.26322200    0.77346400    1.47480900
 C                 -2.44683800    1.40028500    0.31189900
 H                 -3.69841300   -0.19142500    1.18467100
 H                 -2.88579300    1.17570300   -0.66816400
 C                 -2.50137500    2.88414400    0.64355500
 C                 -4.32015800    1.84046700    1.78315600
 C                 -3.59753400    3.12876800    1.47577600
 C                 -3.87340700    4.42225100    1.91036400
 C                 -1.64506100    3.90946800    0.25614500
 C                 -1.91328200    5.20264500    0.71112400
 C                 -3.02159600    5.45907100    1.52252400
 H                 -1.25276900    6.02267700    0.42402400
 H                 -3.21672000    6.47648200    1.86640800
 H                 -0.80717100    3.70346300   -0.40971600
 H                 -4.72875900    4.61975600    2.55961600
 C                  2.12796900   -0.32031600   -0.50754900
 C                  2.40812800   -1.69015700   -0.52854700
 C                  2.99184500    0.65524900   -1.01462800
 C                  3.61265700   -2.08376100   -1.11154100
 C                  4.18502500    0.20987300   -1.58921300
 C                  4.50823400   -1.14991000   -1.64823100
 H                  3.85624900   -3.14812200   -1.15415400
 H                  4.87798900    0.94585100   -2.00355100
 H                 -4.67194600    1.75767600    2.82016500
 H                 -5.18622300    1.71339100    1.11234900
 C                  2.62614400    2.11271800   -0.94155600
 H                  1.64110400    2.30909700   -1.39768100
 H                  2.56881600    2.44325700    0.10764900
 H                  3.37728200    2.72754100   -1.45271400
 C                  1.41290600   -2.67844700    0.01022600
 H                  0.49110600   -2.66539500   -0.59410500
 H                  1.81975000   -3.69672500   -0.01207300
 H                  1.13285500   -2.43561800    1.04592500
 C                  5.80870100   -1.60650000   -2.25145400
 H                  6.55025600   -1.80621800   -1.46226800
 H                  5.67792200   -2.53717500   -2.82024600
 H                  6.22986900   -0.84437300   -2.91978200
 C                 -0.74488700   -0.14263200   -1.96214800
 C                  0.18824800   -0.48660100   -2.96650000
 O                 -1.97918000   -0.15242600   -2.11681300
 C                 -0.30412800   -1.40497400   -4.05140000
 H                 -1.27038700   -1.02771800   -4.41828700
 H                  0.39384100   -1.37426000   -4.90163400
 H                  1.23984800   -0.57611700   -2.69621400
 C                  0.28324600    1.42719700   -4.02792300
 C                  0.46574700    1.16217300   -5.39984800
 C                 -0.86612400    2.10119100   -3.38413100
 H                  1.20100200    1.67331400   -3.49169300
 C                 -0.48799600    1.00656200   -6.40021200
 C                 -2.21010600    2.05745900   -3.92911200
 C                 -1.86833800    1.16326500   -6.29907500
 C                 -2.59832000    1.60785400   -5.19066600
 H                 -2.45347100    0.94315900   -7.19439600
 H                 -3.67809500    1.66104400   -5.36215300
 O                 -0.64493300    2.59196600   -2.26490900
 H                  1.50254000    0.98642400   -5.70103500
 H                 -0.10438100    0.72714700   -7.38567500
 C                 -3.30019100    2.58049400   -3.05320600
 C                 -3.27994300    3.89301700   -2.56352100
 C                 -4.39663500    1.76563800   -2.73566100
 C                 -4.33405700    4.38388100   -1.79440700
 H                 -2.42246100    4.52995600   -2.78608500
 C                 -5.44336400    2.24907800   -1.95165900
 H                 -4.39385200    0.72983200   -3.08094900
 C                 -5.41657300    3.56326600   -1.47993400
 H                 -4.29794000    5.40850200   -1.41910200
 H                 -6.28210200    1.59507900   -1.70375600
 H                 -6.23340200    3.94363700   -0.86327000
 C                 -0.46214300   -2.84474500   -3.56314600
 H                 -0.80587000   -3.50691800   -4.37242000
 H                  0.49275200   -3.24359600   -3.18597700
 H                 -1.20054200   -2.89540700   -2.74866900

 1 3 1.5 5 1.5 47 1.0
 2 4 2.0 5 1.5 6 1.0
 3 4 1.0 25 1.0
 4
 5 11 1.0
 6 7 1.0 8 1.0 9 1.0
 7
 8
 9 10 1.0
 10 11 1.0 12 1.0 15 1.0
 11 13 1.0 14 1.0
 12
 13
 14 16 1.5 18 1.5
 15 16 1.0 33 1.0 34 1.0
 16 17 1.5
 17 20 1.5 24 1.0
 18 19 1.5 23 1.0
 19 20 1.5 21 1.0
 20 22 1.0
 21
 22
 23
 24
 25 26 1.5 27 1.5
 26 28 1.5 39 1.0
 27 29 1.5 35 1.0
 28 30 1.5 31 1.0
 29 30 1.5 32 1.0
 30 43 1.0
 31
 32
 33
 34
 35 36 1.0 37 1.0 38 1.0
 36
 37
 38
 39 40 1.0 41 1.0 42 1.0
 40
 41
 42
 43 44 1.0 45 1.0 46 1.0
 44
 45
 46
 47 48 1.5 49 2.0
 48 50 1.0 53 1.0
 49
 50 51 1.0 52 1.0 78 1.0
 51
 52
 53
 54 55 1.5 56 1.0 57 1.0
 55 58 1.5 65 1.0
 56 59 1.0 64 2.0
 57
 58 60 1.5 66 1.0
 59 61 1.5 67 1.0
 60 61 1.5 62 1.0
 61 63 1.0
 62
 63
 64
 65
 66
 67 68 1.5 69 1.5
 68 70 1.5 71 1.0
 69 72 1.5 73 1.0
 70 74 1.5 75 1.0
 71
 72 74 1.5 76 1.0
 73
 74 77 1.0
 75
 76
 77
 78 79 1.0 80 1.0 81 1.0
 79
 80
 81

alpha=1.2

