%nprocshared=24
%mem=123GB
%chk=Prod_Trans_UD_3.chk
#p opt=maxcyc=500 freq=noraman scrf=(smd,solvent=dichloroethane,read)
nosymm pop=full geom=connectivity def2svp empiricaldispersion=gd3
iop(6/80=1) rm062x scf=(maxcycle=250,xqc)

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0 1
 C                 -0.43728700   -2.17130500    0.44190200
 C                  0.00249000   -0.84099400   -0.15248600
 O                 -0.18511400   -3.27187900    0.06840300
 C                  1.53986400   -0.73188600   -0.04170600
 H                  1.97589100   -1.58482200   -0.58221800
 H                  1.85546100    0.18572600   -0.55714000
 C                  2.02170400   -0.71614600    1.38938900
 C                  2.13189800   -1.90553700    2.12272700
 C                  2.31711200    0.49065500    2.03418100
 C                  2.51159200   -1.89366100    3.46297200
 H                  1.92398500   -2.86295500    1.63938200
 C                  2.69969600    0.52117700    3.37400200
 H                  2.25544300    1.42982500    1.47912300
 C                  2.79003000   -0.67576200    4.07959200
 H                  2.59433800   -2.82624600    4.02137600
 H                  2.92817800    1.46854300    3.86248300
 H                 -0.27444300   -0.84119800   -1.21597300
 C                 -0.77520500    0.20590100    0.65336800
 C                 -1.92213500    0.88612500   -0.05041700
 C                 -1.34899800   -0.61601300    1.77729800
 H                 -0.11150300    0.97758100    1.07823000
 C                 -2.66160100    1.81740400    0.57985200
 C                 -1.95261100   -0.10327300    2.86486800
 C                 -2.56091800    2.15736700    1.99024200
 C                 -2.26276600    1.30588600    3.00631900
 H                 -2.86652100    3.16824100    2.27228100
 H                 -2.35158300    1.66912000    4.03305600
 O                 -1.17675900   -1.94972800    1.56941300
 H                 -2.12821700    0.63060800   -1.09377700
 H                 -3.41228500    2.36465600    0.00288200
 Br                 3.31198000   -0.64793900    5.90151300
 C                 -2.37576087   -1.03677277    4.01426888
 C                 -3.00696418   -2.24859818    3.73225298
 C                 -2.12790954   -0.67086310    5.33723070
 C                 -3.39080185   -3.09395115    4.77305495
 H                 -3.20291446   -2.53643217    2.68918209
 C                 -2.51091499   -1.51681332    6.37842470
 H                 -1.63027289    0.28412658    5.55967503
 C                 -3.14239746   -2.72814570    6.09657230
 H                 -3.88889182   -4.04885282    4.55087104
 H                 -2.31499598   -1.22823562    7.42140739
 H                 -3.44507796   -3.39486601    6.91703855

 1 2 1.0 3 2.0 28 1.0
 2 4 1.0 17 1.0 18 1.0
 3
 4 5 1.0 6 1.0 7 1.0
 5
 6
 7 8 1.5 9 1.5
 8 10 1.5 11 1.0
 9 12 1.5 13 1.0
 10 14 1.5 15 1.0
 11
 12 14 1.5 16 1.0
 13
 14 31 1.0
 15
 16
 17
 18 19 1.0 20 1.0 21 1.0
 19 22 2.0 29 1.0
 20 23 2.0 28 1.0
 21
 22 24 1.0 30 1.0
 23 25 1.0 32 1.0
 24 25 2.0 26 1.0
 25 27 1.0
 26
 27
 28
 29
 30
 31
 32 33 1.5 34 1.5
 33 35 1.5 36 1.0
 34 37 1.5 38 1.0
 35 39 1.5 40 1.0
 36
 37 39 1.5 41 1.0
 38
 39 42 1.0
 40
 41
 42

alpha=1.2


