%nprocshared=24
%mem=123GB
%chk=T4Anti_Si_Down_Cis_1.chk
#p opt=(calcfc,ts,noeigentest,maxcyc=500,z-matrix) freq=noraman
scrf=(smd,solvent=dichloroethane,read) nosymm pop=full geom=connectivity
def2svp empiricaldispersion=gd3 iop(6/80=1) rm062x scf=(maxcycle=250,xqc)

Title Card Required

0 1
 C              
 C                  1            B1
 N                  1            B2    2            A1
 N                  2            B3    1            A2    3            D1    0
 N                  1            B4    3            A3    4            D2    0
 C                  2            B5    1            A4    3            D3    0
 H                  6            B6    2            A5    1            D4    0
 H                  6            B7    2            A6    1            D5    0
 O                  6            B8    2            A7    1            D6    0
 C                  9            B9    6            A8    2            D7    0
 C                  5           B10    1            A9    3            D8    0
 H                 10           B11    9           A10    6            D9    0
 H                 11           B12    5           A11    1           D10    0
 C                 11           B13    5           A12    1           D11    0
 C                 10           B14    9           A13    6           D12    0
 C                 14           B15   11           A14    5           D13    0
 C                 16           B16   14           A15   11           D14    0
 C                 14           B17   11           A16    5           D15    0
 C                 18           B18   14           A17   11           D16    0
 C                 19           B19   18           A18   14           D17    0
 H                 19           B20   18           A19   14           D18    0
 H                 20           B21   19           A20   18           D19    0
 H                 18           B22   14           A21   11           D20    0
 H                 17           B23   16           A22   14           D21    0
 C                  3           B24    1           A23    5           D22    0
 C                 25           B25    3           A24    1           D23    0
 C                 25           B26    3           A25    1           D24    0
 C                 26           B27   25           A26    3           D25    0
 C                 27           B28   25           A27    3           D26    0
 C                 29           B29   27           A28   25           D27    0
 H                 28           B30   26           A29   25           D28    0
 H                 29           B31   27           A30   25           D29    0
 H                 15           B32   10           A31    9           D30    0
 H                 15           B33   10           A32    9           D31    0
 C                 27           B34   25           A33    3           D32    0
 H                 35           B35   27           A34   25           D33    0
 H                 35           B36   27           A35   25           D34    0
 H                 35           B37   27           A36   25           D35    0
 C                 26           B38   25           A37    3           D36    0
 H                 39           B39   26           A38   25           D37    0
 H                 39           B40   26           A39   25           D38    0
 H                 39           B41   26           A40   25           D39    0
 C                 30           B42   29           A41   27           D40    0
 H                 43           B43   30           A42   29           D41    0
 H                 43           B44   30           A43   29           D42    0
 H                 43           B45   30           A44   29           D43    0
 C                  1           B46    3           A45    4           D44    0
 C                 47           B47    1           A46    3           D45    0
 H                 48           B48   47           A47    1           D46    0
 O                 47           B49    1           A48    3           D47    0
 C                 48           B50   47           A49    1           D48    0
 H                 51           B51   48           A50   47           D49    0
 H                 51           B52   48           A51   47           D50    0
 C                 51           B53   48           A52   47           D51    0
 C                 54           B54   51           A53   48           D52    0
 C                 54           B55   51           A54   48           D53    0
 C                 55           B56   54           A55   51           D54    0
 H                 55           B57   54           A56   51           D55    0
 C                 56           B58   54           A57   51           D56    0
 H                 56           B59   54           A58   51           D57    0
 C                 59           B60   56           A59   54           D58    0
 H                 57           B61   55           A60   54           D59    0
 H                 59           B62   56           A61   54           D60    0
 H                 61           B63   59           A62   56           D61    0
 C                 48           B64   47           A63    1           D62    0
 C                 65           B65   48           A64   47           D63    0
 C                 65           B66   48           A65   47           D64    0
 H                 65           B67   48           A66   47           D65    0
 C                 66           B68   65           A67   48           D66    0
 O                 66           B69   65           A68   48           D67    0
 C                 67           B70   65           A69   48           D68    0
 H                 67           B71   65           A70   48           D69    0
 C                 69           B72   66           A71   65           D70    0
 Cl                69           B73   66           A72   65           D71    0
 C                 71           B74   67           A73   65           D72    0
 H                 71           B75   67           A74   65           D73    0
 H                 73           B76   69           A75   66           D74    0
 H                 75           B77   71           A76   67           D75    0

   B1             2.16969400
   B2             1.33118600
   B3             1.29833815
   B4             1.34249265
   B5             1.49660960
   B6             1.09716436
   B7             1.10454279
   B8             1.39829307
   B9             1.39999802
   B10            1.48821187
   B11            1.09801117
   B12            1.09695366
   B13            1.51034628
   B14            1.54449874
   B15            1.40167320
   B16            1.39177966
   B17            1.39298331
   B18            1.39656998
   B19            1.39694551
   B20            1.09129567
   B21            1.09155579
   B22            1.08882271
   B23            1.09149318
   B24            1.43820028
   B25            1.40206956
   B26            1.39849208
   B27            1.39492172
   B28            1.39657924
   B29            1.39764058
   B30            1.09214212
   B31            1.09305223
   B32            1.10322076
   B33            1.09757555
   B34            1.50206088
   B35            1.09807078
   B36            1.10174651
   B37            1.09814963
   B38            1.50552277
   B39            1.10144956
   B40            1.10081076
   B41            1.09718352
   B42            1.50399729
   B43            1.10149823
   B44            1.09820204
   B45            1.09895268
   B46            1.50560216
   B47            1.41500868
   B48            1.09248969
   B49            1.24080773
   B50            1.50471954
   B51            1.10074047
   B52            1.10028291
   B53            1.51319465
   B54            1.40246553
   B55            1.39957053
   B56            1.39397620
   B57            1.09299510
   B58            1.39513044
   B59            1.09336490
   B60            1.39439391
   B61            1.09214112
   B62            1.09210260
   B63            1.09181564
   B64            2.20223397
   B65            1.48357409
   B66            1.41006404
   B67            1.08779005
   B68            1.44927471
   B69            1.23643543
   B70            1.39269601
   B71            1.09341127
   B72            1.38472836
   B73            1.75582958
   B74            1.39171617
   B75            1.09415187
   B76            1.09324187
   B77            1.09095866
   A1            68.78543714
   A2            74.94574643
   A3           106.15005333
   A4           157.76812515
   A5           109.66768350
   A6           108.41930846
   A7           110.86797914
   A8           115.03466087
   A9           130.53752492
   A10          105.63222351
   A11          106.90013620
   A12          115.53304894
   A13          117.92673475
   A14          109.41545494
   A15          120.04223723
   A16          129.05704929
   A17          118.42003892
   A18          120.48833159
   A19          119.71631661
   A20          119.58821382
   A21          120.34435814
   A22          120.69274313
   A23          127.04640521
   A24          117.86488490
   A25          118.84319956
   A26          117.12295225
   A27          117.15952780
   A28          121.82060883
   A29          118.70247003
   A30          118.63669764
   A31          111.70842546
   A32          112.57605732
   A33          121.31230291
   A34          112.27953024
   A35          110.60142861
   A36          110.82043223
   A37          121.71033700
   A38          110.88570088
   A39          112.19377037
   A40          110.24413960
   A41          120.63818193
   A42          110.68943888
   A43          111.24650797
   A44          111.22014889
   A45          126.15720571
   A46          115.28915037
   A47          116.92635829
   A48          116.03228841
   A49          116.72831688
   A50          108.44158448
   A51          109.90166190
   A52          111.15589713
   A53          120.52487744
   A54          120.89915309
   A55          120.67644788
   A56          118.60776802
   A57          120.88628137
   A58          119.24161838
   A59          120.11327156
   A60          119.75693929
   A61          119.79929879
   A62          120.21650201
   A63          103.38273439
   A64           98.87241606
   A65          106.65155208
   A66           91.70440028
   A67          121.03952229
   A68          117.64065355
   A69          129.47036455
   A70          114.52535808
   A71          130.74544848
   A72          113.56178034
   A73          128.07759305
   A74          115.84819842
   A75          113.85679117
   A76          117.31985462
   D1             0.83955620
   D2            -3.29255692
   D3           167.70286404
   D4           149.34799687
   D5           -93.19816996
   D6            29.92860902
   D7           -46.22171060
   D8          -174.90416568
   D9          -178.92657716
   D10           77.34190641
   D11          -50.68415488
   D12          -57.13870310
   D13          -89.04978098
   D14         -178.42663136
   D15           97.15252903
   D16          176.02857956
   D17            0.21175943
   D18          179.87799541
   D19          179.22845188
   D20           -5.68067194
   D21         -179.37792347
   D22          169.97164171
   D23          -64.06074817
   D24          115.87273130
   D25          178.45117119
   D26         -178.50228664
   D27           -0.31102084
   D28         -179.18592068
   D29          178.86075276
   D30           48.83348460
   D31          -74.16421011
   D32            1.06118288
   D33          -28.19021334
   D34           90.72217518
   D35         -149.96207372
   D36           -2.29344188
   D37          -51.57438866
   D38           68.80138288
   D39         -171.08227537
   D40         -179.86180074
   D41           79.87724392
   D42         -160.33238462
   D43          -39.26667534
   D44          177.53320920
   D45          -50.65243820
   D46           20.47604348
   D47          131.72744172
   D48          164.66708053
   D49           40.83549836
   D50          158.49095369
   D51          -79.97402860
   D52           82.53628798
   D53          -95.21283921
   D54         -178.23748443
   D55            1.40443480
   D56          178.29038313
   D57           -1.94147557
   D58           -0.18687970
   D59         -179.67999387
   D60          179.61798519
   D61          179.68455142
   D62          -80.91427849
   D63           88.48185310
   D64         -136.92246213
   D65          -21.10221660
   D66          106.87782129
   D67          -72.52574457
   D68          -89.52247929
   D69           83.63144758
   D70           -9.92536815
   D71          173.25428623
   D72          -11.89865298
   D73          170.35482197
   D74         -171.33106553
   D75          178.11231161

 1 3 1.5 5 1.5 47 1.0
 2 4 2.0 5 1.5 6 1.0
 3 4 1.0 25 1.0
 4
 5 11 1.0
 6 7 1.0 8 1.0 9 1.0
 7
 8
 9 10 1.0
 10 11 1.0 12 1.0 15 1.0
 11 13 1.0 14 1.0
 12
 13
 14 16 1.5 18 1.5
 15 16 1.0 33 1.0 34 1.0
 16 17 1.5
 17 20 1.5 24 1.0
 18 19 1.5 23 1.0
 19 20 1.5 21 1.0
 20 22 1.0
 21
 22
 23
 24
 25 26 1.5 27 1.5
 26 28 1.5 39 1.0
 27 29 1.5 35 1.0
 28 30 1.5 31 1.0
 29 30 1.5 32 1.0
 30 43 1.0
 31
 32
 33
 34
 35 36 1.0 37 1.0 38 1.0
 36
 37
 38
 39 40 1.0 41 1.0 42 1.0
 40
 41
 42
 43 44 1.0 45 1.0 46 1.0
 44
 45
 46
 47 48 1.5 50 2.0
 48 49 1.0 51 1.0
 49
 50
 51 52 1.0 53 1.0 54 1.0
 52
 53
 54 55 1.5 56 1.5
 55 57 1.5 58 1.0
 56 59 1.5 60 1.0
 57 61 1.5 62 1.0
 58
 59 61 1.5 63 1.0
 60
 61 64 1.0
 62
 63
 64
 65 66 1.0 67 1.5 68 1.0
 66 69 1.0 70 2.0
 67 71 1.5 72 1.0
 68
 69 73 2.0 74 1.0
 70
 71 75 1.5 76 1.0
 72
 73 75 1.5 77 1.0
 74
 75 78 1.0
 76
 77
 78

alpha=1.2

