%nproc=8
%Mem=8000MB
%Chk=Tsl_prod
#p SCRF(SMD,Solvent=toluene) B3LYP/gen EmpiricalDispersion=GD3 nosymm
# scf(maxcyc=400,XQC) gfinput gfprint pop=full 

opt freq

0 1
C                 -0.14955500    0.29937400   -3.19045500
 C                 -0.46897300    1.66131800   -3.18172800
 C                  0.48227200    2.60031300   -2.78874700
 C                  1.76711600    2.19459000   -2.40263100
 C                  2.08052700    0.83220000   -2.41927000
 C                  1.12696000   -0.11359100   -2.80671200
 H                 -0.89015800   -0.43232700   -3.50266400
 H                 -1.45641900    1.99087900   -3.49418400
 H                  0.24436000    3.66002800   -2.81395500
 H                  3.08208300    0.51153500   -2.14210600
 H                  1.38672500   -1.16899600   -2.81840300
 C                  2.81035200    3.21246100   -1.98616800
 H                  3.77827300    2.70553500   -1.88878500
 C                  2.49534100    3.95937100   -0.67559900
 H                  1.42499600    4.19321900   -0.63299300
 H                  2.74393100    3.34947400    0.19777900
 C                  3.32264200    5.24455800   -0.79484200
 H                  4.37837100    5.03256300   -0.58850200
 H                  2.99416700    6.03485200   -0.11294700
 C                  3.14772700    5.64027800   -2.26737300
 H                  4.00906800    6.17060100   -2.67571700
 H                  2.26010500    6.26777300   -2.41395000
 N                  2.93751600    4.33738900   -2.95393000
 S                  3.69055500    4.02798800   -4.42312600
 O                  4.62216700    2.89757200   -4.27388100
 O                  4.16559300    5.32333700   -4.93247800
 C                  2.34519700    3.48116800   -5.46838900
 C                  2.20064900    2.12865800   -5.76486000
 C                  1.42683500    4.42691800   -5.93400500
 C                  1.11025800    1.71778500   -6.53226800
 H                  2.91722200    1.41097800   -5.38350300
 C                  0.34832800    3.99974200   -6.70076000
 H                  1.56071400    5.47812700   -5.69880900
 C                  0.17092400    2.63972500   -7.00917000
 H                  0.98587200    0.66140000   -6.75448700
 H                 -0.37000000    4.72896400   -7.06793300
 C                 -1.01070000    2.19615300   -7.83648900
 H                 -1.95342100    2.55885400   -7.40851300
 H                 -0.95005700    2.59255100   -8.85827200
 H                 -1.06869400    1.10516700   -7.90495800

N C H S O 0
6-311+G**
****

