%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=water) opt=(ts,noeigentest,calcfc) freq

title

0 1
 15           0       -2.587324   -0.768680    0.458061
 46           0       -0.323854   -0.008987    0.038536
 15           0       -0.038387    2.353511   -0.176217
 35           0        1.096908   -1.492750   -1.878887
  6           0        0.789791    3.013208   -1.700605
  1           0        0.845690    4.107767   -1.680463
  1           0        1.802386    2.608651   -1.781712
  1           0        0.226579    2.699325   -2.584217
  6           0        0.927855    3.205597    1.157361
  1           0        1.930279    2.773459    1.216850
  1           0        1.008701    4.282016    0.967148
  1           0        0.431904    3.048566    2.119799
  6           0       -1.591004    3.369272   -0.173302
  1           0       -1.367545    4.439812   -0.249404
  1           0       -2.222766    3.076254   -1.016664
  1           0       -2.145903    3.185769    0.751566
  6           0       -3.980215    0.191262   -0.301041
  1           0       -3.850434    0.223753   -1.386778
  1           0       -4.950121   -0.263523   -0.069539
  1           0       -3.967203    1.217797    0.075365
  6           0       -3.132325   -0.850988    2.228538
  1           0       -3.078917    0.146031    2.675292
  1           0       -4.158391   -1.226808    2.312011
  1           0       -2.462581   -1.511204    2.787223
  6           0       -2.994578   -2.483210   -0.123247
  1           0       -4.038689   -2.739647    0.090619
  1           0       -2.821777   -2.554198   -1.201012
  1           0       -2.339533   -3.203973    0.374650
  6           0        1.683870   -0.688301    0.084221
  6           0        1.475727   -1.620634    1.124076
  6           0        2.838554    0.125173    0.081126
  6           0        2.321040   -1.589469    2.248743
  1           0        0.707492   -2.381140    1.038786
  6           0        3.672852    0.120485    1.193113
  1           0        3.047637    0.771104   -0.764546
  6           0        3.411756   -0.723480    2.291393
  1           0        2.140381   -2.285092    3.064316
  1           0        4.535144    0.782318    1.211018
  1           0        4.078911   -0.723346    3.148162

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD






