%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=water) opt=(ts,noeigentest,calcfc) freq

title

0 1
 Pd                -0.02198400   -0.47740500    0.07184800
 P                 -0.03849564   -2.89345173    0.22158483
 Br                 0.03841500    1.36947800    2.16778600
 C                  1.02786536   -3.76332704    1.46652169
 H                  0.87654774   -4.84781656    1.42472472
 H                  2.08294487   -3.54658252    1.27648211
 H                  0.78168482   -3.40659107    2.47098014
 C                  0.38984336   -3.80974909   -1.33043976
 H                  1.39985375   -3.53755246   -1.64935884
 H                  0.33887452   -4.89379627   -1.17930559
 H                 -0.30777420   -3.52479531   -2.12337369
 C                 -1.69605972   -3.62290831    0.62475418
 H                 -1.65314167   -4.71792784    0.65225956
 H                 -2.03001241   -3.25397611    1.59888340
 H                 -2.42543719   -3.31106153   -0.12821725
 C                  0.07155900    1.63007500   -0.07321000
 C                 -1.12236600    2.18176000   -0.57580200
 C                  1.31548700    2.08654400   -0.54986600
 C                 -1.06600600    3.05895800   -1.66388000
 H                 -2.07482600    1.92450600   -0.12869300
 C                  1.35116800    2.96452900   -1.63779700
 H                  2.23547100    1.75566800   -0.08353400
 C                  0.16547200    3.44705900   -2.20607700
 H                 -1.99308100    3.45042600   -2.07438400
 H                  2.31463300    3.28145700   -2.02836500
 H                  0.20156500    4.13817300   -3.04281600

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD




