%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=water) opt=(modredun,ts,noeigentest,calcfc) freq

title

0 1
 35           0        3.210463   -0.779846   -1.479975
 15           0        0.172879    2.572606    0.306212
 46           0       -0.975543    0.567145    0.032338
 15           0       -2.765818   -0.920900   -0.485594
  6           0       -2.824647   -2.691005    0.041553
  1           0       -3.764098   -3.154533   -0.277930
  1           0       -1.988478   -3.235355   -0.403730
  1           0       -2.739702   -2.760440    1.129597
  6           0       -3.143500   -1.076665   -2.291341
  1           0       -2.305396   -1.562735   -2.798914
  1           0       -4.052319   -1.666682   -2.453896
  1           0       -3.278791   -0.081829   -2.724561
  6           0       -4.364729   -0.274899    0.190167
  1           0       -4.523036    0.749901   -0.156577
  1           0       -5.205518   -0.898069   -0.133520
  1           0       -4.324751   -0.267527    1.283121
  6           0       -0.827409    4.049071   -0.182686
  1           0       -0.267653    4.973390   -0.001504
  1           0       -1.079793    3.983679   -1.244517
  1           0       -1.756230    4.072816    0.393691
  6           0        0.648477    2.997827    2.044498
  1           0        1.152061    3.969837    2.080220
  1           0       -0.252481    3.039731    2.663068
  1           0        1.313405    2.236701    2.462357
  6           0        1.740642    2.834902   -0.632027
  1           0        2.195919    3.797468   -0.375414
  1           0        2.445638    2.027606   -0.418295
  1           0        1.521288    2.814912   -1.703270
  6           0        1.307731   -1.029678    0.353477
  6           0        1.845082   -0.554037    1.534706
  6           0        0.768511   -2.289337    0.171453
  6           0        1.722683   -1.378629    2.664424
  1           0        2.333364    0.407783    1.603338
  6           0        0.675974   -3.100574    1.317007
  1           0        0.426802   -2.648604   -0.791003
  6           0        1.142014   -2.648215    2.555344
  1           0        2.099531   -1.020367    3.618811
  1           0        0.238125   -4.090896    1.222973
  1           0        1.069971   -3.289014    3.428796

3 29 F
1 3 F
2 3 4 F

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD






