%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=water) opt=(ts,noeigentest,calcall) freq

title

0 1
 15           0       -2.173151   -1.435515   -0.266000
 46           0        0.021738   -0.477051    0.074944
 15           0        2.283950   -1.259178   -0.285689
 35           0       -0.031843    1.379009    2.165445
  6           0        3.657701   -0.680202    0.819275
  1           0        4.609907   -1.146038    0.541578
  1           0        3.762682    0.406453    0.751439
  1           0        3.423992   -0.936316    1.856875
  6           0        3.003466   -0.937314   -1.962692
  1           0        3.040993    0.140126   -2.145844
  1           0        4.013952   -1.352553   -2.047017
  1           0        2.363724   -1.391796   -2.724803
  6           0        2.491517   -3.098067   -0.155237
  1           0        3.525776   -3.395723   -0.362693
  1           0        2.220212   -3.427316    0.851998
  1           0        1.825585   -3.591563   -0.868834
  6           0       -2.230909   -3.284011   -0.119136
  1           0       -1.924135   -3.580509    0.888097
  1           0       -3.239569   -3.666745   -0.313297
  1           0       -1.534024   -3.729232   -0.834910
  6           0       -2.921758   -1.185084   -1.942013
  1           0       -2.256011   -1.603745   -2.702375
  1           0       -3.901494   -1.670103   -2.015603
  1           0       -3.034053   -0.114910   -2.136957
  6           0       -3.585530   -0.961326    0.840368
  1           0       -4.496572   -1.507597    0.571380
  1           0       -3.327312   -1.186929    1.879252
  1           0       -3.781430    0.111937    0.762471
  6           0       -0.074751    1.631886   -0.073635
  6           0       -1.321233    2.084752   -0.547324
  6           0        1.116817    2.182046   -0.583876
  6           0       -1.362107    2.957587   -1.639226
  1           0       -2.238998    1.754907   -0.075834
  6           0        1.055011    3.054026   -1.675894
  1           0        2.071589    1.927440   -0.140136
  6           0       -0.179144    3.438720   -2.214513
  1           0       -2.327454    3.271630   -2.027432
  1           0        1.980058    3.444009   -2.092314
  1           0       -0.219343    4.125914   -3.054281

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD

