%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=water) opt=(ts,noeigentest,calcfc) freq

title

0 1
 15           0       -2.183959   -1.420784   -0.269860
 46           0        0.019040   -0.477883    0.072436
 15           0        2.277544   -1.271915   -0.283334
 35           0       -0.031452    1.375869    2.166687
  6           0        3.651125   -0.698263    0.824573
  1           0        4.602587   -1.165907    0.547440
  1           0        3.759056    0.388216    0.759015
  1           0        3.415310   -0.955746    1.861340
  6           0        3.003765   -0.956437   -1.958805
  1           0        3.050070    0.120469   -2.143167
  1           0        4.011447   -1.379137   -2.039742
  1           0        2.363014   -1.407072   -2.722328
  6           0        2.475849   -3.111682   -0.149695
  1           0        3.508967   -3.414470   -0.355176
  1           0        2.201558   -3.438131    0.857646
  1           0        1.808697   -3.603155   -0.863552
  6           0       -2.255660   -3.267665   -0.109737
  1           0       -1.956367   -3.558256    0.901481
  1           0       -3.265795   -3.645179   -0.306434
  1           0       -1.557842   -3.723214   -0.818064
  6           0       -2.923547   -1.175672   -1.950546
  1           0       -2.255870   -1.600288   -2.705836
  1           0       -3.904882   -1.657047   -2.026806
  1           0       -3.030849   -0.105933   -2.150868
  6           0       -3.597257   -0.928482    0.827329
  1           0       -4.511255   -1.469604    0.558033
  1           0       -3.345139   -1.149348    1.868708
  1           0       -3.784937    0.145647    0.741738
  6           0       -0.062891    1.631317   -0.073022
  6           0       -1.304537    2.092551   -0.551207
  6           0        1.134017    2.175068   -0.577447
  6           0       -1.335596    2.966757   -1.642368
  1           0       -2.226207    1.767821   -0.083929
  6           0        1.082153    3.048638   -1.668694
  1           0        2.085250    1.914377   -0.129737
  6           0       -0.147357    3.441149   -2.212298
  1           0       -2.297410    3.287035   -2.034223
  1           0        2.011298    3.433572   -2.080660
  1           0       -0.179853    4.129349   -3.051575

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD

