%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=water) opt=(ts,noeigentest,calcall) freq

title

0 1
  15           0       -2.197029   -1.402710   -0.272474
  46           0        0.015375   -0.478871    0.068724
  15           0        2.268068   -1.288962   -0.282102
  35           0       -0.026010    1.371996    2.167560
   6           0        3.636460   -0.740671    0.844843
   1           0        4.585795   -1.215330    0.572378
   1           0        3.756006    0.345265    0.791079
   1           0        3.387836   -1.005913    1.876648
   6           0        3.012772   -0.960793   -1.947041
   1           0        3.074854    0.117720   -2.116750
   1           0        4.015561   -1.395568   -2.024833
   1           0        2.373057   -1.392793   -2.722115
   6           0        2.448278   -3.131927   -0.168807
   1           0        3.480389   -3.441571   -0.368916
   1           0        2.162110   -3.468091    0.832003
   1           0        1.783026   -3.608375   -0.894541
   6           0       -2.285053   -3.249120   -0.115195
   1           0       -1.983126   -3.544240    0.893917
   1           0       -3.299636   -3.617022   -0.307248
   1           0       -1.595184   -3.709854   -0.827939
   6           0       -2.935424   -1.148371   -1.952235
   1           0       -2.275731   -1.585215   -2.707607
   1           0       -3.924528   -1.613872   -2.026594
   1           0       -3.025346   -0.077379   -2.154293
   6           0       -3.604514   -0.899333    0.827055
   1           0       -4.523098   -1.433117    0.558774
   1           0       -3.352714   -1.122528    1.868022
   1           0       -3.783677    0.176288    0.741943
   6           0       -0.047712    1.630718   -0.072490
   6           0       -1.284385    2.101907   -0.553913
   6           0        1.154744    2.167212   -0.571461
   6           0       -1.305478    2.978666   -1.643306
   1           0       -2.210011    1.783083   -0.090408
   6           0        1.112857    3.043616   -1.660810
   1           0        2.102539    1.898733   -0.121043
   6           0       -0.111955    3.445962   -2.207918
   1           0       -2.263650    3.306617   -2.037727
   1           0        2.046111    3.422974   -2.068637
   1           0       -0.136632    4.136281   -3.045719

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD

