%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=water) opt=(ts,noeigentest,calcfc) freq

title

0 1
 P                 -1.30506400   -1.76723400    1.25955100
 Pd                -0.99465300    0.16953100   -0.02354800
 P                 -3.26946000    0.77181900   -0.61327600
 Br                 1.88029100   -1.76509100   -0.64421900
 C                  0.98228300    0.46104100    0.14108100
 C                  1.62825000    0.80223700    1.34685900
 C                  0.93738000    1.35773800   -0.94904400
 C                  2.15510900    2.08305300    1.47655700
 H                  1.67920100    0.09453700    2.16718000
 C                  1.47965100    2.65496600   -0.78308500
 H                  0.62182100    1.02923600   -1.93583200
 C                  2.08218700    3.01288200    0.41651900
 H                  2.61151000    2.37422200    2.41917900
 H                  1.46462400    3.34618500   -1.62162800
 H                  2.51298800    4.00229500    0.53729400
 F                 -1.49514004   -3.17778431    0.46512106
 F                 -0.12506727   -2.22243929    2.28779993
 F                 -4.53513207   -0.01319433    0.04908968
 F                 -3.73130105    0.65885030   -2.17239143
 F                 -3.78587555    2.29282825   -0.33624560
 F                 -2.58048178   -1.88961175    2.26713880

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD





