%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=water) opt=(ts,noeigentest,calcfc) freq

title

0 1
 46           0        1.181854   -0.101183   -0.014808
 15           0       -1.164787    0.065700   -0.004674
 35           0        2.989715   -2.098583    0.019950
  6           0        3.222268    0.071956   -0.015325
  6           0        3.605560    0.628216   -1.252818
  6           0        3.587884    0.674921    1.205651
  6           0        4.297916    1.844103   -1.255161
  1           0        3.373891    0.117469   -2.181097
  6           0        4.279875    1.890745    1.171989
  1           0        3.343654    0.199353    2.149304
  6           0        4.637811    2.473327   -0.050535
  1           0        4.579297    2.292920   -2.203847
  1           0        4.547205    2.375401    2.106997
  1           0        5.189118    3.408645   -0.064444
  6           0       -1.813690    1.523148   -0.937497
  6           0       -2.995270    1.495034   -1.694370
  6           0       -1.072547    2.716641   -0.881334
  6           0       -3.426033    2.636552   -2.377201
  1           0       -3.581346    0.583138   -1.756594
  6           0       -1.509864    3.858586   -1.553845
  1           0       -0.145916    2.746917   -0.312084
  6           0       -2.687499    3.819636   -2.306333
  1           0       -4.340889    2.598771   -2.962231
  1           0       -0.927567    4.774190   -1.497308
  1           0       -3.024221    4.705256   -2.837886
  6           0       -2.071241   -1.370460   -0.732345
  6           0       -3.291786   -1.850058   -0.232153
  6           0       -1.491913   -2.012915   -1.840252
  6           0       -3.919429   -2.946882   -0.830279
  1           0       -3.754390   -1.372528    0.626377
  6           0       -2.125783   -3.099769   -2.444082
  1           0       -0.536225   -1.662837   -2.224258
  6           0       -3.340585   -3.570972   -1.937554
  1           0       -4.861669   -3.310608   -0.429597
  1           0       -1.666671   -3.584271   -3.301431
  1           0       -3.830037   -4.423344   -2.400350
  6           0       -1.893231    0.255920    1.682154
  6           0       -1.280682   -0.434719    2.742507
  6           0       -3.014500    1.056158    1.952135
  6           0       -1.785931   -0.338164    4.040031
  1           0       -0.400899   -1.044148    2.548611
  6           0       -3.512982    1.159998    3.254013
  1           0       -3.499379    1.603155    1.149095
  6           0       -2.902425    0.462310    4.298631
  1           0       -1.302677   -0.879389    4.848825
  1           0       -4.379393    1.786046    3.449001
  1           0       -3.290950    0.545314    5.309780

-F -P -Br 0
6-31+G(d,p)
****
-C -H 0
6-31G(d)
****
4 5 6 7 9 11 0
SP   1 1.00       0.000000000000
0.4380000000D-01  0.1000000000D+01  0.1000000000D+01
****
8 10 12 13 14 0
P   1 1.00       0.000000000000
0.1100000000D+01  0.1000000000D+01
****
Pd 0
SDD
****

Pd 0
SDD




