%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=water) opt=(ts,noeigentest,calcfc) freq

title

0 1
 P                  4.00826695   -3.58461074   -1.27686598
 Pd                 2.27196725   -1.98622269   -0.85522920
 P                  2.47213775    0.33903363   -0.43726517
 C                  5.72783352   -2.94986862   -1.55767415
 C                  5.86737312   -1.74233136   -2.26326518
 C                  6.88497098   -3.59298693   -1.09163646
 C                  7.12956871   -1.20210494   -2.51391521
 H                  4.97931134   -1.21674617   -2.60415331
 C                  8.14781598   -3.04293028   -1.32883871
 H                  6.80277425   -4.52210910   -0.53652952
 C                  8.27424044   -1.85030167   -2.04326091
 H                  7.21433869   -0.26791517   -3.06273255
 H                  9.03306810   -3.55065681   -0.95417853
 H                  9.25751293   -1.42483133   -2.22609434
 C                  4.23109690   -4.85598393    0.04745080
 C                  4.66077029   -6.16868823   -0.20620421
 C                  3.94445457   -4.48185922    1.37045922
 C                  4.81032754   -7.08098971    0.84052151
 H                  4.87100273   -6.48262660   -1.22474177
 C                  4.10148949   -5.39287259    2.41677835
 H                  3.57823866   -3.47920806    1.57448635
 C                  4.53431492   -6.69414950    2.15388239
 H                  5.14077371   -8.09460698    0.62815049
 H                  3.87158076   -5.08836842    3.43443192
 H                  4.64752333   -7.40642967    2.96698014
 C                  3.69546356   -4.61868463   -2.78343810
 C                  2.45811933   -5.28474368   -2.86575510
 C                  4.59055434   -4.72541684   -3.85737132
 C                  2.13531442   -6.04842134   -3.98654219
 H                  1.74813981   -5.20161074   -2.04619901
 C                  4.25743599   -5.48017273   -4.98719669
 H                  5.54946166   -4.21833050   -3.81768511
 C                  3.03324385   -6.14495631   -5.05455175
 H                  1.17926019   -6.56404516   -4.02875587
 H                  4.96253243   -5.55010735   -5.81169641
 H                  2.77791508   -6.73373918   -5.93162849
 C                  0.89431717    1.27914688   -0.17194562
 C                 -0.12134836    0.64502394    0.56733575
 C                  0.64677440    2.55853086   -0.69333401
 C                 -1.34156394    1.28326807    0.79502033
 H                  0.04279235   -0.35618543    0.95890398
 C                 -0.58155345    3.18962106   -0.47665613
 H                  1.41250769    3.06655015   -1.27109128
 C                 -1.57652439    2.55692878    0.26999145
 H                 -2.11136253    0.77932974    1.37359211
 H                 -0.75675927    4.17914529   -0.89125412
 H                 -2.53032803    3.04994613    0.43820703
 C                  3.34785290    1.37674154   -1.70070930
 C                  4.17829438    2.45895590   -1.37028604
 C                  3.17465639    1.05248802   -3.05651793
 C                  4.81671108    3.19685538   -2.37061715
 H                  4.33408844    2.72252424   -0.32844746
 C                  3.80288654    1.79617536   -4.05662627
 H                  2.55217108    0.20276379   -3.32652529
 C                  4.62924523    2.86975273   -3.71496657
 H                  5.46023700    4.02900757   -2.09662535
 H                  3.65454958    1.53129261   -5.10037321
 H                  5.12672247    3.44466449   -4.49159335
 C                  3.43107930    0.68680118    1.10898675
 C                  2.95977536    1.50800215    2.14381227
 C                  4.68359624    0.06384807    1.25875350
 C                  3.72079357    1.69991381    3.30120654
 H                  1.99470230    1.99597584    2.05303641
 C                  5.44774712    0.27023301    2.40667930
 H                  5.05981944   -0.58528888    0.47270476
 C                  4.96595417    1.08551576    3.43509365
 H                  3.33719076    2.33543536    4.09532972
 H                  6.41629836   -0.21392191    2.50105931
 H                  5.55700264    1.23761589    4.33435466
 C                  0.09994266   -2.82955415   -0.85632403
 C                  0.31863188   -4.02616718   -1.53952511
 C                 -0.14110206   -2.84485357    0.51743414
 C                  0.29559403   -5.23781424   -0.84916115
 H                  0.50787616   -4.01382987   -2.62270385
 C                 -0.16320230   -4.05670580    1.20832894
 H                 -0.31330671   -1.90181409    1.05609092
 C                  0.05495571   -5.25310956    0.52527539
 H                  0.46733615   -6.18108891   -1.38770925
 H                 -0.35287271   -4.06842772    2.29154727
 H                  0.03689674   -6.20856694    1.06939983
 Br                -2.19700444   -3.01789463   -1.26149298

-F -P -Br 0
6-31+G(d,p)
****
-C -H 0
6-31G(d)
****
70 71 72 73 75 77 0
SP   1 1.00       0.000000000000
0.4380000000D-01  0.1000000000D+01  0.1000000000D+01
****
74 76 78 79 80 0
P   1 1.00       0.000000000000
0.1100000000D+01  0.1000000000D+01
****
Pd 0
SDD
****

Pd 0
SDD










