%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=water) opt=(ts,noeigentest,calcfc) freq

title

0 1
 P                  2.14014600    0.19745800   -0.09968000
 Pd                -0.14100100   -0.62193600   -0.15980100
 P                 -1.95743400    0.88701200    0.02879500
 C                  2.46878400    2.00979200    0.12363000
 C                  3.43398859    2.61292289   -0.69961732
 C                  1.79403162    2.80453113    1.06410223
 C                  3.73149534    3.97134056   -0.57472068
 H                  3.95242382    2.01859169   -1.44524809
 C                  2.08196323    4.16774727    1.17864941
 H                  1.03882537    2.36511473    1.70756540
 C                  3.05243274    4.75367975    0.36310063
 H                  4.48434680    4.41730638   -1.21857666
 H                  1.54633920    4.76910733    1.90814184
 H                  3.27491944    5.81313208    0.45422533
 C                  3.08576100   -0.56346600    1.29014100
 C                  4.46521900   -0.81829000    1.21457400
 C                  2.39743200   -0.89106600    2.46866200
 C                  5.14331500   -1.37551000    2.30183100
 H                  5.01207500   -0.58732500    0.30494300
 C                  3.07903100   -1.43648800    3.55936400
 H                  1.32441000   -0.73163000    2.52769300
 C                  4.45270800   -1.68063900    3.47789800
 H                  6.21023700   -1.56750200    2.22926500
 H                  2.53341900   -1.68273500    4.46630000
 H                  4.98081300   -2.11232800    4.32353900
 C                  3.15454600   -0.16089800   -1.64210700
 C                  2.64303056   -0.75236724   -2.82271118
 C                  4.49272685    0.27833551   -1.68005682
 C                  3.44916394   -0.92642742   -3.94996233
 H                  1.62181333   -1.07652758   -2.90570236
 C                  5.29383808    0.11063148   -2.81332899
 H                  4.93036252    0.75364391   -0.81096699
 C                  4.77820772   -0.49900326   -3.95467467
 H                  3.02102303   -1.39253239   -4.83255065
 H                  6.32256026    0.46000209   -2.79334023
 H                  5.39612351   -0.63144922   -4.83816926
 C                 -3.17901179    0.60769389    1.39862758
 C                 -2.74088834    0.04869722    2.61005280
 C                 -4.54441794    0.90720505    1.25226051
 C                 -3.63560264   -0.16887428    3.66021720
 H                 -1.70549337   -0.24640773    2.72649686
 C                 -5.44087526    0.67565353    2.29880377
 H                 -4.91287113    1.33066543    0.32404742
 C                 -4.98851588    0.14348812    3.50787885
 H                 -3.27428814   -0.59913311    4.59008711
 H                 -6.49264302    0.91385896    2.16573565
 H                 -5.68599257   -0.03641968    4.32114304
 C                 -3.05689579    1.05348840   -1.44503112
 C                 -3.59961897    2.27829126   -1.86193116
 C                 -3.36034020   -0.10956953   -2.17345086
 C                 -4.43060647    2.33695649   -2.98458796
 H                 -3.37186326    3.18853549   -1.31555353
 C                 -4.19899765   -0.05110834   -3.28777866
 H                 -2.93022807   -1.06160100   -1.87035639
 C                 -4.73304400    1.17439998   -3.69758390
 H                 -4.84192921    3.29222624   -3.29886991
 H                 -4.42697434   -0.95860724   -3.83998207
 H                 -5.37872226    1.22269875   -4.56986860
 C                 -1.34607695    2.60393990    0.35022184
 C                 -1.77986247    3.36813933    1.44505377
 C                 -0.37797975    3.14861196   -0.51313769
 C                 -1.25818836    4.64608689    1.67045377
 H                 -2.52250575    2.96968041    2.12822207
 C                  0.12988264    4.42927051   -0.29399420
 H                 -0.02168784    2.57236061   -1.36096408
 C                 -0.30527693    5.18074579    0.80217097
 H                 -1.60318519    5.22203399    2.52477381
 H                  0.87066245    4.83706953   -0.97637644
 H                  0.09701273    6.17461067    0.97712024
 C                 -0.65483800   -2.66671000   -0.09092100
 C                  0.59963000   -2.91427400   -0.68493700
 C                 -0.84813500   -3.00086900    1.28329100
 C                  1.63298400   -3.52280000    0.06220600
 H                  0.71156100   -2.70499700   -1.74331400
 C                  0.16931300   -3.61600200    1.99352800
 H                 -1.78507900   -2.75666500    1.77890200
 C                  1.40906700   -3.89801100    1.37874400
 H                  2.59353600   -3.73286400   -0.40270300
 H                  0.01621400   -3.86708500    3.04150600
 H                  2.19552500   -4.38914700    1.94662900
 Br                -2.08155200   -4.29139100   -1.04823800

-F -P -Br 0
6-31+G(d,p)
****
-C -H 0
6-31G(d)
****
70 71 72 73 75 77 0
SP   1 1.00       0.000000000000
0.4380000000D-01  0.1000000000D+01  0.1000000000D+01
****
74 76 78 79 80 0
P   1 1.00       0.000000000000
0.1100000000D+01  0.1000000000D+01
****
Pd 0
SDD
****

Pd 0
SDD










