%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=water) opt=(ts,noeigentest,calcfc) freq

title

0 1
 P                  2.29431000   -0.36137100    0.24488600
 Pd                 0.22144600   -0.98410300   -0.64460800
 Br                -0.57297900    2.32994300   -0.13030800
 C                 -1.32210800   -0.01631400    0.09794900
 C                 -1.72076400   -0.22407800    1.43571600
 C                 -2.15424500   -0.38483700   -0.98274000
 C                 -2.92853200   -0.87285300    1.67555500
 H                 -1.08710900    0.09752600    2.25420700
 C                 -3.36949600   -1.04981000   -0.70263100
 H                 -1.92732300   -0.07488900   -1.99836000
 C                 -3.75532100   -1.29045200    0.61202500
 H                 -3.22790800   -1.06797900    2.70213600
 H                 -4.01692600   -1.33441400   -1.52794600
 H                 -4.69765500   -1.78701400    0.82278500
 C                  2.21726560    0.31566293    1.93251428
 C                  1.55616095   -0.39051117    2.93786507
 C                  2.81921554    1.54043184    2.22086390
 C                  1.49648874    0.12836445    4.23108936
 H                  1.08103515   -1.35570086    2.71003590
 C                  2.76046369    2.05913416    3.51465910
 H                  3.34046359    2.09705453    1.42865138
 C                  2.09912737    1.35341192    4.51971006
 H                  0.97487705   -0.42789264    5.02342503
 H                  3.23552013    3.02463792    3.74181122
 H                  2.05199762    1.76229892    5.53945833
 C                  3.52449318   -1.69473928    0.39041385
 C                  4.79737347   -1.53221851   -0.15715734
 C                  3.19482943   -2.87903333    1.04944158
 C                  5.74009479   -2.55408031   -0.04626674
 H                  5.05671288   -0.59872802   -0.67733073
 C                  4.13804372   -3.90091481    1.16131178
 H                  2.19170521   -3.00722201    1.48122681
 C                  5.41048421   -3.73869117    0.61348360
 H                  6.74320915   -2.42630011   -0.47838977
 H                  3.87796894   -4.83440615    1.68133990
 H                  6.15397067   -4.54422985    0.70084295
 C                  3.19517226    0.92609110   -0.67342142
 C                  2.64946873    1.46156834   -1.84044465
 C                  4.43105910    1.37754297   -0.21047104
 C                  3.33987968    2.44778981   -2.54466171
 H                  1.67545756    1.10489042   -2.20558147
 C                  5.12135088    2.36476271   -0.91424964
 H                  4.86122201    0.95573926    0.70940424
 C                  4.57606058    2.89981948   -2.08125853
 H                  2.91010531    2.86945851   -3.46487147
 H                  6.09558343    2.72081129   -0.54877107
 H                  5.12021318    3.67746986   -2.63664504

-F -P -Br 0
6-31+G(d,p)
****
-C -H 0
6-31G(d)
****
4 5 6 7 9 11 0
SP   1 1.00       0.000000000000
0.4380000000D-01  0.1000000000D+01  0.1000000000D+01
****
8 10 12 13 14 0
P   1 1.00       0.000000000000
0.1100000000D+01  0.1000000000D+01
****
Pd 0
SDD
****

Pd 0
SDD




