%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcfc) freq

title

0 1
 Pd                -0.40152200    0.18831200   -0.01625700
 P                 -2.75346696   -0.27705507   -0.27990631
 Br                 2.93253200   -0.70058400   -1.10862400
 C                  1.52527900    0.77224700    0.18045300
 C                  2.14181300    0.98453200    1.44168900
 C                  1.09663300    1.88744400   -0.59766800
 C                  2.25224100    2.27597700    1.93509200
 H                  2.48956900    0.13932000    2.02649600
 C                  1.25336200    3.19911400   -0.07210500
 H                  0.86273700    1.77231800   -1.65282500
 C                  1.81422300    3.39215300    1.17987800
 H                  2.67061500    2.42956700    2.92702000
 H                  0.97071800    4.05060900   -0.68653500
 H                  1.93700300    4.39499300    1.57837400
 C                 -3.67781664   -0.64594536    1.24387111
 H                 -4.70045128   -0.84630128    1.00102160
 H                 -3.25031686   -1.50250294    1.72183873
 H                 -3.62611788    0.19409323    1.90459981
 C                 -3.24086227   -1.64179240   -1.38096844
 H                 -2.82391805   -2.55834415   -1.01904247
 H                 -4.30784616   -1.71919894   -1.40226626
 H                 -2.87736804   -1.45017934   -2.36892410
 C                 -3.70970299    1.10966264   -0.96912807
 H                 -3.31657303    1.37170204   -1.92917192
 H                 -4.73490919    0.82051363   -1.07034617
 H                 -3.63980923    1.95204005   -0.31306773

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD






