%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcall) freq

title

0 1
 15           0        2.591485    0.361279   -0.427531
 46           0        0.196227    0.409091    0.076690
 15           0       -1.479156    2.114871   -0.122030
 35           0       -0.196392   -1.410107    2.117212
  6           0       -2.865232    2.222974    1.108595
  1           0       -3.507916    3.086203    0.901581
  1           0       -3.474963    1.315801    1.073394
  1           0       -2.451831    2.317989    2.116845
  6           0       -2.411618    2.169312   -1.722324
  1           0       -2.927143    1.217755   -1.879634
  1           0       -3.145540    2.983143   -1.729765
  1           0       -1.707235    2.314368   -2.546496
  6           0       -0.820529    3.847765   -0.032529
  1           0       -1.620878    4.586640   -0.156634
  1           0       -0.337080    4.004765    0.936180
  1           0       -0.072136    3.993902   -0.816525
  6           0        3.475110    1.969990   -0.150372
  1           0        3.382368    2.261096    0.899954
  1           0        4.537802    1.890768   -0.407265
  1           0        3.015168    2.750493   -0.763318
  6           0        3.077551   -0.009932   -2.178231
  1           0        2.616007    0.723053   -2.846009
  1           0        4.165721    0.022854   -2.305031
  1           0        2.714461   -1.002464   -2.460153
  6           0        3.697391   -0.800126    0.506017
  1           0        4.746287   -0.667395    0.217161
  1           0        3.594937   -0.618045    1.579629
  1           0        3.404648   -1.835771    0.309801
  6           0       -0.777877   -1.450508   -0.080257
  6           0        0.021613   -2.323179   -0.840262
  6           0       -2.171611   -1.420764   -0.271866
  6           0       -0.555956   -3.030739   -1.901969
  1           0        1.072077   -2.445559   -0.606688
  6           0       -2.731164   -2.139727   -1.330563
  1           0       -2.799293   -0.840608    0.393753
  6           0       -1.927726   -2.936628   -2.158236
  1           0        0.072818   -3.673952   -2.512092
  1           0       -3.803352   -2.082864   -1.499887
  1           0       -2.372278   -3.499468   -2.973569

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD







