%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcall) freq

title

0 1
 P                 -2.20111800   -1.38085200   -0.29260900
 Pd                 0.00935900   -0.47123000    0.08522400
 P                  2.24776400   -1.31310700   -0.28607100
 Br                -0.03000800    1.33951800    2.17251100
 C                  3.63931200   -0.77160300    0.81651900
 H                  4.57911800   -1.26192800    0.53798600
 H                  3.77243200    0.31204100    0.74987500
 H                  3.39974800   -1.01991600    1.85456800
 C                  2.97425200   -1.00522600   -1.96333200
 H                  3.03314900    0.07145200   -2.14550600
 H                  3.97593400   -1.44130200   -2.04984600
 H                  2.32395000   -1.44365300   -2.72589600
 C                  2.41703900   -3.15717300   -0.16122100
 H                  3.44467600   -3.47738000   -0.36891300
 H                  2.13796300   -3.48371800    0.84479500
 H                  1.74087700   -3.63471200   -0.87609100
 C                 -2.31617400   -3.22893700   -0.16551400
 H                 -2.02356900   -3.54538300    0.83987300
 H                 -3.33478500   -3.57979500   -0.36855800
 H                 -1.62919700   -3.68787700   -0.88224700
 C                 -2.93380500   -1.09531100   -1.97087100
 H                 -2.27260600   -1.52002400   -2.73184900
 H                 -3.92457100   -1.55566900   -2.05695500
 H                 -3.01820200   -0.02077800   -2.15570600
 C                 -3.60853900   -0.87975400    0.80874800
 H                 -4.53463300   -1.39356100    0.52677600
 H                 -3.36422200   -1.12539700    1.84634100
 H                 -3.76969200    0.20022200    0.74597000
 C                 -0.02852400    1.63139900   -0.07706600
 C                 -1.25395400    2.12466100   -0.56286600
 C                  1.18432700    2.16184900   -0.55496500
 C                 -1.25407500    3.02398600   -1.63379300
 H                 -2.18758500    1.80828000   -0.11371000
 C                  1.16416000    3.06076000   -1.62611300
 H                  2.12358400    1.87361400   -0.09878900
 C                 -0.04996900    3.48865900   -2.17681400
 H                 -2.20409600    3.37286800   -2.03024900
 H                  2.10564100    3.43866800   -2.01626900
 H                 -0.05815000    4.19693600   -2.99986700

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD







