%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcfc) freq

title

0 1
 P                 -0.42132300   -2.08634500    0.58755800
 Pd                -0.40152200    0.18831200   -0.01625700
 P                 -2.71939200    0.75195900   -0.37333300
 Br                 2.93253200   -0.70058400   -1.10862400
 C                  1.52527900    0.77224700    0.18045300
 C                  2.14181300    0.98453200    1.44168900
 C                  1.09663300    1.88744400   -0.59766800
 C                  2.25224100    2.27597700    1.93509200
 H                  2.48956900    0.13932000    2.02649600
 C                  1.25336200    3.19911400   -0.07210500
 H                  0.86273700    1.77231800   -1.65282500
 C                  1.81422300    3.39215300    1.17987800
 H                  2.67061500    2.42956700    2.92702000
 H                  0.97071800    4.05060900   -0.68653500
 H                  1.93700300    4.39499300    1.57837400
 C                 -2.98253659    2.44010316   -1.00048866
 H                 -4.02141836    2.58393579   -1.21247178
 H                 -2.66780766    3.14791113   -0.26234668
 H                 -2.41308954    2.58094249   -1.89535979
 C                 -3.66906807   -0.23635596   -1.57072554
 H                 -3.79626122   -1.22916815   -1.19251150
 H                 -4.62816956    0.21291152   -1.72298539
 H                 -3.14109920   -0.27385332   -2.50064104
 C                 -1.88533670   -2.74550440    1.44463020
 H                 -2.67723233   -2.88845847    0.73938879
 H                 -1.64024228   -3.68204271    1.90039848
 H                 -2.19924650   -2.05353960    2.19798627
 C                 -0.24480421   -3.22377147   -0.82222998
 H                  0.62362679   -2.95828975   -1.38813373
 H                 -0.14275331   -4.22590305   -0.46137278
 H                 -1.11150865   -3.15582810   -1.44601448
 C                  0.92420152   -2.61079616    1.69521984
 H                  1.86591037   -2.45098641    1.21299036
 H                  0.88498331   -2.03977397    2.59926386
 H                  0.81276065   -3.64995919    1.92461281
 C                 -3.79005974    0.73022465    1.09826417
 H                 -4.67777546    1.29438702    0.90184212
 H                 -4.05394944   -0.27993143    1.33245834
 H                 -3.26791251    1.16344052    1.92566147

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD





