%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcfc) freq

title

0 1
 Pd                -0.39810100   -0.85387600   -0.00580300
 P                 -2.34721300    0.16266100   -0.00051900
 Br                 1.95524400   -1.63345200    0.00525700
 C                  1.37934000    0.50735700    0.00200200
 C                  1.53786100    1.16013800   -1.22427300
 C                  1.52631900    1.16607600    1.22666400
 C                  1.76659200    2.54052800   -1.21232600
 H                  1.47182900    0.61670800   -2.15962100
 C                  1.75534100    2.54644600    1.20977200
 H                  1.45160000    0.62726900    2.16404700
 C                  1.87122900    3.23596100   -0.00251100
 H                  1.86695000    3.06610200   -2.15765000
 H                  1.84668600    3.07689700    2.15329200
 H                  2.05784200    4.30532000   -0.00429200
 C                 -2.97112770    0.92962425    1.52751824
 H                 -3.92274592    1.38042261    1.33750873
 H                 -3.07584049    0.18134784    2.28515777
 H                 -2.28160351    1.67800910    1.85823943
 C                 -3.89706955   -0.67884327   -0.45020247
 H                 -4.07052337   -1.49119573    0.22425825
 H                 -4.70982372    0.01448489   -0.38998010
 H                 -3.82204058   -1.05454931   -1.44925984
 C                 -2.58964377    1.61881213   -1.06506173
 H                 -2.44070112    1.34172596   -2.08777349
 H                 -3.58436597    1.99197472   -0.93787129
 H                 -1.88639209    2.37882421   -0.79539765

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD




