%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcall) freq

title

0 1
 P                 -2.17745800   -1.41380500   -0.29523000
 Pd                 0.01918600   -0.46988900    0.08578700
 P                  2.27008000   -1.27814400   -0.28290800
 Br                -0.06049900    1.33960300    2.17285600
 C                  3.65483100   -0.70995900    0.81481900
 H                  4.60000300   -1.19335200    0.54235200
 H                  3.77682800    0.37415900    0.73556600
 H                  3.41720900   -0.94886900    1.85549300
 C                  2.99125800   -0.96868400   -1.96236000
 H                  3.03779000    0.10776100   -2.14950400
 H                  3.99796100   -1.39336500   -2.04776900
 H                  2.34555600   -1.41803700   -2.72245500
 C                  2.46717400   -3.11882300   -0.14904400
 H                  3.49855300   -3.42426200   -0.36000600
 H                  2.19775300   -3.44452300    0.85987900
 H                  1.79496800   -3.60986700   -0.85849400
 C                 -2.26675000   -3.26092900   -0.13757600
 H                 -1.97721800   -3.55506900    0.87546300
 H                 -3.27829100   -3.63097900   -0.34213700
 H                 -1.56718800   -3.72206800   -0.84058500
 C                 -2.89622500   -1.16578200   -1.98510200
 H                 -2.22473500   -1.60039200   -2.73132500
 H                 -3.88299400   -1.63445400   -2.07211500
 H                 -2.98564100   -0.09549800   -2.19098800
 C                 -3.60327000   -0.91531400    0.78339900
 H                 -4.51704800   -1.45238200    0.50469400
 H                 -3.36364800   -1.13386900    1.82812700
 H                 -3.78441700    0.15973000    0.69547400
 C                 -0.05626900    1.63118000   -0.07678200
 C                 -1.28811000    2.10385400   -0.56680800
 C                  1.14905000    2.18137200   -0.55114600
 C                 -1.29974100    3.00131300   -1.63920300
 H                 -2.21787500    1.77260200   -0.12040300
 C                  1.11748500    3.07803700   -1.62396800
 H                  2.09120200    1.90969500   -0.09091100
 C                 -0.10173600    3.48464100   -2.17948300
 H                 -2.25417400    3.33363600   -2.03928100
 H                  2.05381000    3.47098800   -2.01165000
 H                 -0.11901200    4.19101700   -3.00403200

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD







