%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcfc) freq

title

0 1
 Pd                -0.02198400   -0.47740500    0.07184800
 P                  2.17663700   -1.43034700   -0.27158000
 Br                 0.03841500    1.36947800    2.16778600
 C                  3.59107700   -0.94566300    0.82756400
 H                  4.50275500   -1.49108300    0.55900900
 H                  3.78398600    0.12760300    0.74287500
 H                  3.33659700   -1.16560300    1.86855800
 C                  2.91842800   -1.18537500   -1.95133900
 H                  3.02213000   -0.11561300   -2.15327100
 H                  3.90141300   -1.66371300   -2.02570900
 H                  2.25306400   -1.61324800   -2.70687100
 C                  2.24183000   -3.27788300   -0.11495400
 H                  3.25171400   -3.65839700   -0.30733300
 H                  1.93642200   -3.56964200    0.89408800
 H                  1.54613900   -3.72979500   -0.82769200
 C                  0.07155900    1.63007500   -0.07321000
 C                 -1.12236600    2.18176000   -0.57580200
 C                  1.31548700    2.08654400   -0.54986600
 C                 -1.06600600    3.05895800   -1.66388000
 H                 -2.07482600    1.92450600   -0.12869300
 C                  1.35116800    2.96452900   -1.63779700
 H                  2.23547100    1.75566800   -0.08353400
 C                  0.16547200    3.44705900   -2.20607700
 H                 -1.99308100    3.45042600   -2.07438400
 H                  2.31463300    3.28145700   -2.02836500
 H                  0.20156500    4.13817300   -3.04281600

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD





