%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcall) freq

title

0 1
 P                  2.54320500    0.40281717   -0.62004568
 Pd                 0.19622700    0.40909100    0.07669000
 P                 -1.49839652    2.10739872    0.08592375
 Br                -0.37462316   -1.31979371    2.15333364
 C                 -2.78119326    2.15203915    1.42747904
 H                 -3.44287458    3.01769247    1.30964873
 H                 -3.38714653    1.24198889    1.40292270
 H                 -2.28827897    2.20822017    2.40235108
 C                 -2.55720324    2.22094052   -1.43046231
 H                 -3.07888511    1.27246586   -1.58608051
 H                 -3.29346969    3.02810037   -1.34430858
 H                 -1.92236328    2.40639644   -2.30169159
 C                 -0.84353316    3.84055408    0.19568732
 H                 -1.65504030    4.57715187    0.16781793
 H                 -0.28430635    3.96091616    1.12818257
 H                 -0.16159117    4.02578012   -0.63902477
 C                  3.43810374    2.00594994   -0.34676397
 H                  3.42892763    2.25197665    0.71902923
 H                  4.47699340    1.94660113   -0.69139483
 H                  2.92623512    2.80752099   -0.88704977
 C                  2.88831611    0.10945835   -2.41833575
 H                  2.37066872    0.86583956   -3.01511543
 H                  3.96252623    0.15677874   -2.63070454
 H                  2.50872473   -0.87343498   -2.71204516
 C                  3.72673159   -0.78725470    0.17140568
 H                  4.74821158   -0.63362199   -0.19494628
 H                  3.71030959   -0.65121182    1.25653963
 H                  3.42439178   -1.81621601   -0.04443920
 C                 -0.77787700   -1.45050800   -0.08025700
 C                  0.07268074   -2.35872663   -0.73602904
 C                 -2.15139107   -1.42182659   -0.38477243
 C                 -0.42365333   -3.10778064   -1.81028201
 H                  1.09988717   -2.47642833   -0.41353630
 C                 -2.63010704   -2.18223714   -1.45409628
 H                 -2.82560121   -0.81073866    0.20312771
 C                 -1.76952982   -3.01764866   -2.18011341
 H                  0.24664750   -3.77951687   -2.34018486
 H                 -3.68468880   -2.12715351   -1.71161179
 H                 -2.15186005   -3.61233082   -3.00434637

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD







