%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcall) freq

title

0 1
  15           0       -2.595565   -0.659348    0.497137
  46           0       -0.326745    0.022777   -0.000493
  15           0        0.068526    2.365963   -0.251953
  35           0        0.932816   -1.714825   -1.740702   
   6           0        0.898594    2.984196   -1.794035
   1           0        1.013529    4.074209   -1.775226
   1           0        1.885746    2.525014   -1.897099
   1           0        0.299720    2.702201   -2.665079   
   6           0        1.093731    3.184340    1.059165
   1           0        2.074387    2.703759    1.111044
   1           0        1.225060    4.253394    0.855981
   1           0        0.603588    3.062449    2.029738
   6           0       -1.436853    3.451183   -0.231227
   1           0       -1.168582    4.510371   -0.321951
   1           0       -2.096672    3.178403   -1.059843
   1           0       -1.982039    3.300201    0.705223
   6           0       -3.973675    0.338795   -0.241013
   1           0       -3.877988    0.342169   -1.330775
   1           0       -4.953402   -0.070234    0.031441
   1           0       -3.906417    1.372078    0.110651
   6           0       -3.094931   -0.683213    2.283969
   1           0       -2.986024    0.318851    2.708883
   1           0       -4.133795   -1.011868    2.402677
   1           0       -2.440101   -1.361455    2.838847
   6           0       -3.088994   -2.368749   -0.031015
   1           0       -4.135159   -2.578181    0.220741
   1           0       -2.953123   -2.471615   -1.111498
   1           0       -2.447557   -3.103979    0.463615
   6           0        1.660975   -0.768961    0.070759
   6           0        1.466694   -1.573083    1.213996
   6           0        2.841079   -0.004950   -0.066311
   6           0        2.360217   -1.455182    2.292769
   1           0        0.657798   -2.294220    1.247269
   6           0        3.722957    0.077532    1.005623
   1           0        3.034199    0.539676   -0.984196
   6           0        3.482081   -0.632945    2.197965
   1           0        2.189887   -2.049438    3.186880
   1           0        4.607296    0.703451    0.915964
   1           0        4.185709   -0.567078    3.022346

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD







