%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcall) freq

title

0 1
  15           0       -2.281239   -1.258639   -0.286773
  46           0       -0.023272   -0.469886    0.084949
  15           0        2.165423   -1.432465   -0.291458
  35           0        0.062193    1.338867    2.172962
   6           0        3.592231   -0.949675    0.793010
   1           0        4.501905   -1.494574    0.516064
   1           0        3.783639    0.123838    0.708101
   1           0        3.347155   -1.168347    1.836446
   6           0        2.892241   -1.187222   -1.978296
   1           0        2.992444   -0.117349   -2.181315
   1           0        3.874864   -1.664952   -2.062929
   1           0        2.219333   -1.613779   -2.727881
   6           0        2.237163   -3.280714   -0.137957
   1           0        3.245863   -3.659587   -0.340373
   1           0        1.941856   -3.574634    0.873478
   1           0        1.535520   -3.733656   -0.844217
   6           0       -2.495546   -3.097424   -0.153673
   1           0       -2.230218   -3.425796    0.855471
   1           0       -3.529452   -3.393363   -0.365843
   1           0       -1.827093   -3.594476   -0.862481
   6           0       -2.997267   -0.941711   -1.966992
   1           0       -2.355036   -1.397268   -2.726331
   1           0       -4.008046   -1.356266   -2.053901
   1           0       -3.032659    0.135200   -2.153856
   6           0       -3.661581   -0.677691    0.809732
   1           0       -4.611030   -1.152152    0.536473
   1           0       -3.427001   -0.918895    1.850566
   1           0       -3.773251    0.407548    0.730553
   6           0        0.072763    1.630426   -0.076624
   6           0       -1.125310    2.190703   -0.557525
   6           0        1.311172    2.092908   -0.559797
   6           0       -1.080355    3.087204   -1.630048
   1           0       -2.072283    1.926885   -0.102637
   6           0        1.336192    2.990411   -1.631873
   1           0        2.235649    1.753721   -0.108387
   6           0        0.145229    3.483780   -2.178688
   1           0       -2.011231    3.487984   -2.022812
   1           0        2.295547    3.314808   -2.026653
   1           0        0.172943    4.190117   -3.002987

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD







