%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcall) freq

title

0 1
 P                 -2.27028900   -1.27783500   -0.28287100
 Pd                -0.01926700   -0.46984800    0.08580200
 P                  2.17719300   -1.41414500   -0.29523900
 Br                 0.06076100    1.33967100    2.17283600
 C                  3.60306800   -0.91587400    0.78340900
 H                  4.51677200   -1.45307100    0.50470900
 H                  3.78437600    0.15914400    0.69550900
 H                  3.36339500   -1.13440900    1.82813000
 C                  2.89606200   -1.16636300   -1.98510900
 H                  2.98569200   -0.09611500   -2.19108700
 H                  3.88274700   -1.63523000   -2.07203500
 H                  2.22452400   -1.60091100   -2.73132400
 C                  2.26617200   -3.26128300   -0.13752000
 H                  3.27766700   -3.63149500   -0.34201400
 H                  1.97653600   -3.55535500    0.87550800
 H                  1.56658400   -3.72232900   -0.84056400
 C                 -2.46762000   -3.11845800   -0.14860000
 H                 -2.19833300   -3.44395500    0.86042500
 H                 -3.49901600   -3.42382200   -0.35958600
 H                 -1.79540700   -3.60975200   -0.85787000
 C                 -2.99125600   -0.96865900   -1.96246700
 H                 -2.34547500   -1.41816100   -2.72240600
 H                 -3.99796100   -1.39333000   -2.04792100
 H                 -3.03774800    0.10775500   -2.14980700
 C                 -3.65510200   -0.70922900    0.81455900
 H                 -4.60028400   -1.19262300    0.54213100
 H                 -3.41761000   -0.94785700    1.85532600
 H                 -3.77700700    0.37487600    0.73497500
 C                  0.05657400    1.63120000   -0.07680400
 C                 -1.14868200    2.18155800   -0.55113000
 C                  1.28846600    2.10367700   -0.56688700
 C                 -1.11703100    3.07820100   -1.62396800
 H                 -2.09084600    1.91002400   -0.09083800
 C                  1.30018400    3.00111600   -1.63929800
 H                  2.21820400    1.77229100   -0.12052300
 C                  0.10222800    3.48461400   -2.17953700
 H                 -2.05331400    3.47129000   -2.01161300
 H                  2.25465000    3.33328800   -2.03942500
 H                  0.11957800    4.19097800   -3.00409600

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD







