%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcfc) freq

title

0 1
 P                 -2.58703800   -0.76932500    0.45809800
 Pd                -0.32361400   -0.00962500    0.03912500
 P                 -0.03995300    2.35322500   -0.17651500
 Br                 1.09795400   -1.49240800   -1.87875600
 C                  0.78778000    3.01319300   -1.70105000
 H                  0.84269700    4.10780600   -1.68121800
 H                  1.80077200    2.60954900   -1.78189700
 H                  0.22497100    2.69855700   -2.58465000
 C                  0.92534600    3.20681300    1.15679300
 H                  1.92825000    2.77581700    1.21646400
 H                  1.00502300    4.28324200    0.96616100
 H                  0.42953900    3.04966400    2.11928700
 C                 -1.59362900    3.36737700   -0.17399200
 H                 -1.37142400    4.43813600   -0.25068100
 H                 -2.22516800    3.07318500   -1.01711000
 H                 -2.14821100    3.18375800    0.75105100
 C                 -3.98033500    0.19207700   -0.29841300
 H                 -3.85076600    0.22724700   -1.38409400
 H                 -4.95005500   -0.26357400   -0.06783200
 H                 -3.96756200    1.21769300    0.08048100
 C                 -3.13144100   -0.85567100    2.22857300
 H                 -3.07770800    0.14026200    2.67770400
 H                 -4.15754000   -1.23151900    2.31147100
 H                 -2.46164100   -1.51736400    2.78544100
 C                 -2.99424800   -2.48265400   -0.12680100
 H                 -4.03816300   -2.73979900    0.08715100
 H                 -2.82208500   -2.55125600   -1.20482100
 H                 -2.33871100   -3.20433600    0.36911200
 C                  1.68448000   -0.68734000    0.08415200
 C                  1.47709400   -1.61988800    1.12398200
 C                  2.83855300    0.12703000    0.08104300
 C                  2.32239400   -1.58805100    2.24865900
 H                  0.70957100   -2.38110600    1.03860200
 C                  3.67284200    0.12299200    1.19301900
 H                  3.04704700    0.77320200   -0.76459200
 C                  3.41239500   -0.72118100    2.29131600
 H                  2.14233700   -2.28386500    3.06420300
 H                  4.53458500    0.78553900    1.21095400
 H                  4.07955500   -0.72051300    3.14808200

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD







