%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcall) freq

title

0 1
 P                 -2.58702000   -0.76835400    0.45639500
 Pd                -0.32458200   -0.01914100    0.03644800
 P                 -0.03792900    2.34876100   -0.16127600
 Br                 1.08680200   -1.46768700   -1.88393300
 C                  0.76738800    3.00230100   -1.70078700
 H                  0.83373400    4.09629200   -1.68277600
 H                  1.77437800    2.58782200   -1.80053000
 H                  0.18479900    2.69270000   -2.57336800
 C                  0.95425000    3.19696700    1.15548800
 H                  1.95320100    2.75547900    1.20417100
 H                  1.04279400    4.27167600    0.95964600
 H                  0.46935800    3.04928900    2.12509500
 C                 -1.58512500    3.37237800   -0.13331000
 H                 -1.35850400    4.44197200   -0.21440100
 H                 -2.23182100    3.08153900   -0.96599200
 H                 -2.12546700    3.19213200    0.80075100
 C                 -3.97712500    0.21611100   -0.27608600
 H                 -3.85850700    0.26114000   -1.36264600
 H                 -4.94963200   -0.23066100   -0.03984700
 H                 -3.94832100    1.23750900    0.11319800
 C                 -3.11669400   -0.86665400    2.23128300
 H                 -3.04435500    0.12323400    2.69108400
 H                 -4.14754400   -1.22825400    2.31947100
 H                 -2.45238400   -1.54438600    2.77532900
 C                 -3.01840300   -2.47187400   -0.13967900
 H                 -4.06329900   -2.71905000    0.08111200
 H                 -2.85572100   -2.53438400   -1.21946600
 H                 -2.36699200   -3.20452400    0.34565500
 C                  1.68617200   -0.68915300    0.07882500
 C                  1.48545400   -1.63130100    1.11328900
 C                  2.84043200    0.12528600    0.07759000
 C                  2.33482600   -1.60782600    2.23431500
 H                  0.71386500   -2.38822800    1.02624500
 C                  3.67999400    0.11183900    1.18563500
 H                  3.04483700    0.78019900   -0.76244100
 C                  3.42479800   -0.74072200    2.27881300
 H                  2.15887400   -2.31009400    3.04521000
 H                  4.54171600    0.77439800    1.20426900
 H                  4.09612800   -0.74649900    3.13225500

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD







