%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcall) freq

title

0 1
 P                 -2.58771300   -0.76504100    0.45981800
 Pd                -0.32396300   -0.00779300    0.03760100
 P                 -0.03475300    2.35397800   -0.17918300
 Br                 1.09135300   -1.50079100   -1.87459800
 C                  0.79427500    3.01156500   -1.70404500
 H                  0.85143600    4.10607500   -1.68475200
 H                  1.80641100    2.60578400   -1.78474800
 H                  0.23075400    2.69764600   -2.58745100
 C                  0.93280800    3.20563700    1.15373800
 H                  1.93462800    2.77212200    1.21344100
 H                  1.01516500    4.28181400    0.96278800
 H                  0.43671100    3.04995800    2.11632100
 C                 -1.58587100    3.37206200   -0.17696200
 H                 -1.36082900    4.44222800   -0.25369900
 H                 -2.21801700    3.07946100   -1.02018800
 H                 -2.14112300    3.18993200    0.74796500
 C                 -3.97989500    0.19480900   -0.30074200
 H                 -3.85059700    0.22474000   -1.38661100
 H                 -4.95022600   -0.25832500   -0.06777400
 H                 -3.96548800    1.22216800    0.07336700
 C                 -3.13228100   -0.84317600    2.23063600
 H                 -3.07772700    0.15470600    2.67532300
 H                 -4.15870400   -1.21778200    2.31519300
 H                 -2.46304300   -1.50291700    2.79049100
 C                 -2.99708600   -2.48032400   -0.11781400
 H                 -4.04141400   -2.73516000    0.09691800
 H                 -2.82472200   -2.55373600   -1.19548900
 H                 -2.34268400   -3.20080300    0.38134000
 C                  1.68321700   -0.69100500    0.08385400
 C                  1.47538400   -1.61892000    1.12766500
 C                  2.83891200    0.12097700    0.07588500
 C                  2.32236700   -1.58445400    2.25092300
 H                  0.70563500   -2.37836400    1.04669500
 C                  3.67483200    0.11961200    1.18668200
 H                  3.04760100    0.76324900   -0.77267000
 C                  3.41426900   -0.71969100    2.28862200
 H                  2.14193300   -2.27656000    3.06953100
 H                  4.53800800    0.78038400    1.20069700
 H                  4.08264500   -0.71704400    3.14443400

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD







