%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcall) freq

title

0 1
 P                 -2.58890000   -0.75689100    0.46254500
 Pd                -0.32355700   -0.01422900    0.03187700
 P                 -0.03832500    2.34760000   -0.20000700
 Br                 1.09810300   -1.53307700   -1.85285000
 C                  0.81595100    3.00343200   -1.71169400
 H                  0.86030700    4.09862900   -1.69931200
 H                  1.83440900    2.60935400   -1.76645600
 H                  0.27589700    2.67657000   -2.60498400
 C                  0.90160600    3.20971200    1.14577500
 H                  1.90170600    2.77571500    1.22928600
 H                  0.98917000    4.28416800    0.94766600
 H                  0.38562100    3.06262400    2.09919900
 C                 -1.59518800    3.35631600   -0.23163900
 H                 -1.37671600    4.42784500   -0.30857600
 H                 -2.20891700    3.05546400   -1.08557100
 H                 -2.16693100    3.17386600    0.68313200
 C                 -3.97463100    0.18758000   -0.32819900
 H                 -3.84072400    0.18937100   -1.41395100
 H                 -4.94765900   -0.25578100   -0.08773200
 H                 -3.95713100    1.22400900    0.01981700
 C                 -3.14078300   -0.78746900    2.23281400
 H                 -3.08524100    0.22128800    2.65209500
 H                 -4.16864900   -1.15689600    2.32234400
 H                 -2.47604100   -1.43474500    2.81227200
 C                 -3.00098800   -2.48626400   -0.06972000
 H                 -4.04604500   -2.73315600    0.15056300
 H                 -2.82714100   -2.58986800   -1.14464000
 H                 -2.34860500   -3.19362900    0.45049300
 C                  1.68774100   -0.69022500    0.08570800
 C                  1.48079000   -1.59706400    1.14811800
 C                  2.83973200    0.12692500    0.06349100
 C                  2.32478300   -1.53490900    2.27259100
 H                  0.71460400   -2.36140600    1.08080600
 C                  3.67237900    0.15291400    1.17623400
 H                  3.04701800    0.75197900   -0.79819900
 C                  3.41248500   -0.66441800    2.29495400
 H                  2.14531100   -2.21024200    3.10530300
 H                  4.53247900    0.81782500    1.17881500
 H                  4.07840600   -0.64056600    3.15235100

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD







