%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcall) freq

title

0 1
 P                  2.60184100    0.27901700   -0.40375800
 Pd                 0.21331500    0.39536100    0.10485500
 P                 -1.38691400    2.16662200   -0.13094000
 Br                -0.30610600   -1.41006400    2.12008300
 C                 -2.80409000    2.33215000    1.05722200
 H                 -3.41205400    3.21432200    0.82584000
 H                 -3.44137100    1.44462100    1.01241600
 H                 -2.41676000    2.42181500    2.07634000
 C                 -2.26905300    2.25144200   -1.75857200
 H                 -2.82492000    1.32367800   -1.92082600
 H                 -2.96214400    3.09958800   -1.79404500
 H                 -1.53507700    2.35332200   -2.56320600
 C                 -0.66535700    3.87329500   -0.02589600
 H                 -1.43337800    4.64147300   -0.17371700
 H                 -0.20325500    4.01511700    0.95548600
 H                  0.10956600    3.98877700   -0.78889300
 C                  3.54624735    1.86714872   -0.22527754
 H                  3.51367881    2.19614568    0.81747951
 H                  4.59233305    1.74561973   -0.52951646
 H                  3.08037260    2.64075142   -0.84241305
 C                  2.98513021   -0.16539291   -2.16269607
 H                  2.50409402    0.55441063   -2.83125325
 H                  4.06510943   -0.16462219   -2.34933654
 H                  2.58316505   -1.15769622   -2.38648804
 C                  3.71982190   -0.88471237    0.51319004
 H                  4.75206211   -0.81048849    0.15200963
 H                  3.69578840   -0.64834532    1.58090962
 H                  3.37353773   -1.91478351    0.38700912
 C                 -0.82998600   -1.42941400   -0.08316800
 C                 -0.03976800   -2.32932800   -0.82126800
 C                 -2.21436700   -1.34370100   -0.32162000
 C                 -0.60912800   -3.01306100   -1.90261700
 H                  0.99801400   -2.48921400   -0.55571500
 C                 -2.76589900   -2.03987000   -1.39973400
 H                 -2.84193500   -0.73742900    0.32054400
 C                 -1.96750900   -2.86713500   -2.20203900
 H                  0.01419100   -3.67862700   -2.49408000
 H                 -3.82878600   -1.94076700   -1.60454200
 H                 -2.40683400   -3.41241200   -3.03199600

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD







