%nproc=8
%mem=19000MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcall) freq

title

0 1
 P                 -2.58598500   -0.76818200    0.45504000
 Pd                -0.32378100   -0.01726400    0.03830900
 P                 -0.03286600    2.35151100   -0.15603300
 Br                 1.08302000   -1.45994700   -1.88898500
 C                  0.77818500    3.00497300   -1.69272700
 H                  0.86506500    4.09731100   -1.66487000
 H                  1.77640200    2.57190100   -1.80196300
 H                  0.18548100    2.71482800   -2.56526100
 C                  0.95696200    3.19565900    1.16524800
 H                  1.95281400    2.74813700    1.22107100
 H                  1.05338200    4.26952200    0.96843400
 H                  0.46524000    3.05245700    2.13211800
 C                 -1.57795100    3.37830400   -0.13046300
 H                 -1.34952800    4.44742400   -0.21249600
 H                 -2.22501700    3.08758300   -0.96286100
 H                 -2.11872700    3.20007400    0.80375000
 C                 -3.97648300    0.22594800   -0.26378500
 H                 -3.86029700    0.28232500   -1.35008400
 H                 -4.94909300   -0.22197000   -0.03009400
 H                 -3.94531700    1.24312100    0.13624700
 C                 -3.11216200   -0.88460100    2.22999600
 H                 -3.03576400    0.09978800    2.70081300
 H                 -4.14396700   -1.24398800    2.31630600
 H                 -2.44897900   -1.57057300    2.76505400
 C                 -3.02174700   -2.46437400   -0.15833400
 H                 -4.06569400   -2.71312200    0.06508200
 H                 -2.86508600   -2.51420600   -1.23967600
 H                 -2.36841800   -3.20331400    0.31473600
 C                  1.68350300   -0.69032400    0.07630400
 C                  1.48144000   -1.64217400    1.09954800
 C                  2.83685700    0.12558600    0.08520700
 C                  2.32881100   -1.62935600    2.22251200
 H                  0.71177400   -2.39975600    1.00266600
 C                  3.67441300    0.10178000    1.19437600
 H                  3.04128200    0.79113600   -0.74643200
 C                  3.41823000   -0.76230300    2.27791800
 H                  2.15191700   -2.34010700    3.02575500
 H                  4.53506700    0.76544100    1.22166000
 H                  4.08812200   -0.77639100    3.13239600

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD







