%nproc=8
%mem=18200MB
#p b3lyp/gen pseudo=(read) scrf=(pcm,solvent=thf) opt=(ts,noeigentest,calcfc) freq

title

0 1
 15           0        2.513850   -0.864510    0.811144
 46           0        0.578828   -1.135857   -0.489922
 35           0        0.537486    2.168477   -0.137742
  6           0       -0.846337    0.079817    0.100510
  6           0       -1.364051    0.018519    1.407392
  6           0       -1.665032   -0.076051   -1.033889
  6           0       -2.714383   -0.289202    1.564454
  1           0       -0.723506    0.182538    2.266251
  6           0       -3.022758   -0.405508   -0.839580
  1           0       -1.288189    0.127272   -2.031940
  6           0       -3.544309   -0.506987    0.447777
  1           0       -3.123375   -0.373025    2.567872
  1           0       -3.663753   -0.537625   -1.706978
  1           0       -4.595017   -0.738962    0.592974
  1           0        2.336153   -0.233806    2.059191
  1           0        3.566004   -0.061769    0.321331
  1           0        3.287037   -1.967750    1.241546

-C -F -H -P -Br 0
6-31+G(d,p)
****
Pd 0
SDD
****

Pd 0
SDD





